Theoretical studies of ZEKE spectroscopy and dynamics of high Rydberg states

Yi Hsieh Wang; Yoshiaki Teranishi; H. Mineo; S. D. Chao; H. L. Selzle; H. J. Neusser; E. W. Schlag; S. H. Lin

doi:10.1016/j.cplett.2009.12.092

Theoretical studies of ZEKE spectroscopy and dynamics of high Rydberg states

Yi Hsieh Wang, Yoshiaki Teranishi, H. Mineo, S. D. Chao^*, H. L. Selzle, H. J. Neusser, E. W. Schlag, S. H. Lin

^*Corresponding author for this work

Institute of Physics

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2 Scopus citations

Abstract

A main purpose of this Letter is to show how to employ the inverse Born-Oppenheimer approximation as a basis set to study zero kinetic energy (ZEKE) spectroscopy and the autoionization dynamics of the ZEKE states. The calculations of channel couplings, quantum defects, intensity borrowing, vibrational and rotational autotionizations will be demonstrated by using a homonuclear diatomic molecule as an example.

Original language	English
Pages (from-to)	104-109
Number of pages	6
Journal	Chemical Physics Letters
Volume	486
Issue number	4-6
DOIs	https://doi.org/10.1016/j.cplett.2009.12.092
State	Published - 12 Feb 2010

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10.1016/j.cplett.2009.12.092

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abstract = "A main purpose of this Letter is to show how to employ the inverse Born-Oppenheimer approximation as a basis set to study zero kinetic energy (ZEKE) spectroscopy and the autoionization dynamics of the ZEKE states. The calculations of channel couplings, quantum defects, intensity borrowing, vibrational and rotational autotionizations will be demonstrated by using a homonuclear diatomic molecule as an example.",

author = "Wang, {Yi Hsieh} and Yoshiaki Teranishi and H. Mineo and Chao, {S. D.} and Selzle, {H. L.} and Neusser, {H. J.} and Schlag, {E. W.} and Lin, {S. H.}",

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AU - Wang, Yi Hsieh

AU - Teranishi, Yoshiaki

AU - Mineo, H.

AU - Chao, S. D.

AU - Selzle, H. L.

AU - Neusser, H. J.

AU - Schlag, E. W.

AU - Lin, S. H.

PY - 2010/2/12

Y1 - 2010/2/12

N2 - A main purpose of this Letter is to show how to employ the inverse Born-Oppenheimer approximation as a basis set to study zero kinetic energy (ZEKE) spectroscopy and the autoionization dynamics of the ZEKE states. The calculations of channel couplings, quantum defects, intensity borrowing, vibrational and rotational autotionizations will be demonstrated by using a homonuclear diatomic molecule as an example.

AB - A main purpose of this Letter is to show how to employ the inverse Born-Oppenheimer approximation as a basis set to study zero kinetic energy (ZEKE) spectroscopy and the autoionization dynamics of the ZEKE states. The calculations of channel couplings, quantum defects, intensity borrowing, vibrational and rotational autotionizations will be demonstrated by using a homonuclear diatomic molecule as an example.

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DO - 10.1016/j.cplett.2009.12.092

M3 - Article

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SN - 0009-2614

VL - 486

SP - 104

EP - 109

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 4-6

ER -

Theoretical studies of ZEKE spectroscopy and dynamics of high Rydberg states

Abstract

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