Theoretical studies of autoionization dynamics of high Rydberg states

Yi Hsieh Wang; H. Mineo; S. D. Chao; Yoshiaki Teranishi; S. H. Lin; H. L. Selzle; J. Neusser; E. W. Schlag

doi:10.1088/1742-6596/235/1/012002

Theoretical studies of autoionization dynamics of high Rydberg states

Yi Hsieh Wang^*
, H. Mineo
, S. D. Chao
, Yoshiaki Teranishi
, S. H. Lin
, H. L. Selzle
, J. Neusser
, E. W. Schlag

^*Corresponding author for this work

Institute of Physics

Research output: Contribution to journal › Conference article › peer-review

Abstract

In this paper we show how to employ the inverse Born-Oppenheimer approximation to establish a basis set to study zero kinetic energy (ZEKE) spectroscopy and the autoionization dynamics of the ZEKE Rydberg states. The calculations of vibrational and rotational autoionizations of a homonuclear diatomic molecule will be demonstrated as an example. The scaling laws for the autoionization rate constants are determined through nonlinear modeling of the calculated data.

Original language	English
Article number	012002
Journal	Journal of Physics: Conference Series
Volume	235
Issue number	1
DOIs	https://doi.org/10.1088/1742-6596/235/1/012002
State	Published - 2010
Event	International Workshop on Electronic Spectroscopy for Gas-phase Molecules and Solid Surfaces, IWES2009 - Matsushima, Japan Duration: 12 Oct 2009 → 15 Oct 2009

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title = "Theoretical studies of autoionization dynamics of high Rydberg states",

abstract = "In this paper we show how to employ the inverse Born-Oppenheimer approximation to establish a basis set to study zero kinetic energy (ZEKE) spectroscopy and the autoionization dynamics of the ZEKE Rydberg states. The calculations of vibrational and rotational autoionizations of a homonuclear diatomic molecule will be demonstrated as an example. The scaling laws for the autoionization rate constants are determined through nonlinear modeling of the calculated data.",

author = "Wang, \{Yi Hsieh\} and H. Mineo and Chao, \{S. D.\} and Yoshiaki Teranishi and Lin, \{S. H.\} and Selzle, \{H. L.\} and J. Neusser and Schlag, \{E. W.\}",

year = "2010",

doi = "10.1088/1742-6596/235/1/012002",

language = "English",

volume = "235",

journal = "Journal of Physics: Conference Series",

issn = "1742-6588",

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note = "International Workshop on Electronic Spectroscopy for Gas-phase Molecules and Solid Surfaces, IWES2009 ; Conference date: 12-10-2009 Through 15-10-2009",

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TY - JOUR

T1 - Theoretical studies of autoionization dynamics of high Rydberg states

AU - Wang, Yi Hsieh

AU - Mineo, H.

AU - Chao, S. D.

AU - Teranishi, Yoshiaki

AU - Lin, S. H.

AU - Selzle, H. L.

AU - Neusser, J.

AU - Schlag, E. W.

PY - 2010

Y1 - 2010

N2 - In this paper we show how to employ the inverse Born-Oppenheimer approximation to establish a basis set to study zero kinetic energy (ZEKE) spectroscopy and the autoionization dynamics of the ZEKE Rydberg states. The calculations of vibrational and rotational autoionizations of a homonuclear diatomic molecule will be demonstrated as an example. The scaling laws for the autoionization rate constants are determined through nonlinear modeling of the calculated data.

AB - In this paper we show how to employ the inverse Born-Oppenheimer approximation to establish a basis set to study zero kinetic energy (ZEKE) spectroscopy and the autoionization dynamics of the ZEKE Rydberg states. The calculations of vibrational and rotational autoionizations of a homonuclear diatomic molecule will be demonstrated as an example. The scaling laws for the autoionization rate constants are determined through nonlinear modeling of the calculated data.

UR - https://www.scopus.com/pages/publications/77954766019

U2 - 10.1088/1742-6596/235/1/012002

DO - 10.1088/1742-6596/235/1/012002

M3 - Conference article

AN - SCOPUS:77954766019

SN - 1742-6588

VL - 235

JO - Journal of Physics: Conference Series

JF - Journal of Physics: Conference Series

IS - 1

M1 - 012002

T2 - International Workshop on Electronic Spectroscopy for Gas-phase Molecules and Solid Surfaces, IWES2009

Y2 - 12 October 2009 through 15 October 2009

ER -

Theoretical studies of autoionization dynamics of high Rydberg states

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