The infrared absorption spectrum of hydroxyl radicals in solid argon

Bing Ming Cheng; Yuan-Pern Lee; J. F. Ogilvie

doi:10.1016/0009-2614(88)80079-4

The infrared absorption spectrum of hydroxyl radicals in solid argon

Bing Ming Cheng^*, Yuan-Pern Lee, J. F. Ogilvie

^*Corresponding author for this work

Department of Applied Chemistry

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Abstract

By means of the reaction of atomic H or D (produced either in a microwave discharge or on a W filament) with either NO₂ or O₃ or atomic O, we have prepared and trapped OH and OD radicals in solid Ar at 12 K, characterized by their infrared absorption lines at 354820 and 261610 m^-1, respectively. The reasons for these spectral assignments, and for the rejection of the previously published assignments, are discussed.

Original language	English
Pages (from-to)	109-115
Number of pages	7
Journal	Chemical Physics Letters
Volume	151
Issue number	1-2
DOIs	https://doi.org/10.1016/0009-2614(88)80079-4
State	Published - 7 Oct 1988

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title = "The infrared absorption spectrum of hydroxyl radicals in solid argon",

abstract = "By means of the reaction of atomic H or D (produced either in a microwave discharge or on a W filament) with either NO2 or O3 or atomic O, we have prepared and trapped OH and OD radicals in solid Ar at 12 K, characterized by their infrared absorption lines at 354820 and 261610 m-1, respectively. The reasons for these spectral assignments, and for the rejection of the previously published assignments, are discussed.",

author = "Cheng, {Bing Ming} and Yuan-Pern Lee and Ogilvie, {J. F.}",

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AU - Lee, Yuan-Pern

AU - Ogilvie, J. F.

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Y1 - 1988/10/7

N2 - By means of the reaction of atomic H or D (produced either in a microwave discharge or on a W filament) with either NO2 or O3 or atomic O, we have prepared and trapped OH and OD radicals in solid Ar at 12 K, characterized by their infrared absorption lines at 354820 and 261610 m-1, respectively. The reasons for these spectral assignments, and for the rejection of the previously published assignments, are discussed.

AB - By means of the reaction of atomic H or D (produced either in a microwave discharge or on a W filament) with either NO2 or O3 or atomic O, we have prepared and trapped OH and OD radicals in solid Ar at 12 K, characterized by their infrared absorption lines at 354820 and 261610 m-1, respectively. The reasons for these spectral assignments, and for the rejection of the previously published assignments, are discussed.

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DO - 10.1016/0009-2614(88)80079-4

M3 - Article

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VL - 151

SP - 109

EP - 115

JO - Chemical Physics Letters

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The infrared absorption spectrum of hydroxyl radicals in solid argon

Abstract

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