The effect of cr-doping on the structure, dielectric and magnetic properties of BiFeO3 and Pb(Fe0.5Sb0.5)O3 multiferroics

S. I. Raevskaya; S. P. Kubrin; A. V. Pushkarev; N. M. Olekhnovich; Y. V. Radyush; V. V. Titov; Haydn Chen; C. C. Chou; M. A. Malitskaya; I. P. Raevski; V. V. Stashenko; D. A. Sarychev

doi:10.1007/978-3-319-78919-4_16

The effect of cr-doping on the structure, dielectric and magnetic properties of BiFeO₃ and Pb(Fe_0.5Sb_0.5)O₃ multiferroics

S. I. Raevskaya, S. P. Kubrin, A. V. Pushkarev, N. M. Olekhnovich, Y. V. Radyush, V. V. Titov, Haydn Chen, C. C. Chou, M. A. Malitskaya, I. P. Raevski^*, V. V. Stashenko, D. A. Sarychev

^*Corresponding author for this work

International College of Semiconductor Technology

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

Abstract

X-ray diffraction and Mössbauer studies of perovskite BiFe_1−xCr_xO₃ and PbFe_0.5−xCr_xSb_0.5O₃ solid solution ceramics, fabricated under high pressure (4–6 GPa) have been carried out. Two morphotropic phase boundaries were revealed in the BiFe_1−xCr_xO₃ system: one between rhombohedral (R3c) and orthorhombic (Pbam) phases at x ≈ 0.5–0.6 and the other between the orthorhombic (Pbam) and monoclinic (C2/c) phases at x ≈ 0.9. It was found out that substitution of Cr³⁺ for Fe³⁺ in BiFeO₃ does not lead to the appearance of a low-spin state of Fe³⁺ ions, as was predicted by some first-principles calculations. A composition dependence of the magnetic phase transition temperature for BiFe_1−xCr_xO₃ is very similar to that in the solid solutions of BiFeO₃ with non-magnetic ions, implying the lack of magnetic exchange between Fe³⁺ and Cr³⁺. The reason of such behavior seems to be a difference in their electronic configuration. Addition of Cr to PbFe_0.5Sb_0.5O₃ leads to a dramatic lowering and diffusion of the dielectric permittivity maximum and its shift to lower temperatures. Thus, Cr substitution for Fe seems to destroy both ferroelectric and magnetic long-range order in perovskite multiferroics.

Original language	English
Title of host publication	Advanced Materials - Proceedings of the International Conference on "Physics and Mechanics of New Materials and Their Applications", PHENMA 2017
Editors	Shun-Hsyung Chang, Ivan A. Parinov, Vijay K. Gupta
Publisher	Springer Science and Business Media, LLC
Pages	195-208
Number of pages	14
ISBN (Print)	9783319789187
DOIs	https://doi.org/10.1007/978-3-319-78919-4_16
State	Published - 1 Jan 2018
Event	International Conference on Physics, Mechanics of New Materials and Their Applications, PHENMA 2017 - Jabalapur, India Duration: 14 Oct 2017 → 16 Oct 2017

Publication series

Name	Springer Proceedings in Physics
Volume	207
ISSN (Print)	0930-8989
ISSN (Electronic)	1867-4941

Conference

Conference	International Conference on Physics, Mechanics of New Materials and Their Applications, PHENMA 2017
Country/Territory	India
City	Jabalapur
Period	14/10/17 → 16/10/17

Access to Document

10.1007/978-3-319-78919-4_16

Cite this

Raevskaya, S. I., Kubrin, S. P., Pushkarev, A. V., Olekhnovich, N. M., Radyush, Y. V., Titov, V. V., Chen, H., Chou, C. C., Malitskaya, M. A., Raevski, I. P., Stashenko, V. V., & Sarychev, D. A. (2018). The effect of cr-doping on the structure, dielectric and magnetic properties of BiFeO₃ and Pb(Fe_0.5Sb_0.5)O₃ multiferroics. In S-H. Chang, I. A. Parinov, & V. K. Gupta (Eds.), Advanced Materials - Proceedings of the International Conference on "Physics and Mechanics of New Materials and Their Applications", PHENMA 2017 (pp. 195-208). (Springer Proceedings in Physics; Vol. 207). Springer Science and Business Media, LLC. https://doi.org/10.1007/978-3-319-78919-4_16

Raevskaya, S. I. ; Kubrin, S. P. ; Pushkarev, A. V. et al. / The effect of cr-doping on the structure, dielectric and magnetic properties of BiFeO₃ and Pb(Fe_0.5Sb_0.5)O₃ multiferroics. Advanced Materials - Proceedings of the International Conference on "Physics and Mechanics of New Materials and Their Applications", PHENMA 2017. editor / Shun-Hsyung Chang ; Ivan A. Parinov ; Vijay K. Gupta. Springer Science and Business Media, LLC, 2018. pp. 195-208 (Springer Proceedings in Physics).

@inproceedings{fdea1dc9cb494b219b1658d8023a7dd5,

title = "The effect of cr-doping on the structure, dielectric and magnetic properties of BiFeO3 and Pb(Fe0.5Sb0.5)O3 multiferroics",

abstract = "X-ray diffraction and M{\"o}ssbauer studies of perovskite BiFe1−xCrxO3 and PbFe0.5−xCrxSb0.5O3 solid solution ceramics, fabricated under high pressure (4–6 GPa) have been carried out. Two morphotropic phase boundaries were revealed in the BiFe1−xCrxO3 system: one between rhombohedral (R3c) and orthorhombic (Pbam) phases at x ≈ 0.5–0.6 and the other between the orthorhombic (Pbam) and monoclinic (C2/c) phases at x ≈ 0.9. It was found out that substitution of Cr3+ for Fe3+ in BiFeO3 does not lead to the appearance of a low-spin state of Fe3+ ions, as was predicted by some first-principles calculations. A composition dependence of the magnetic phase transition temperature for BiFe1−xCrxO3 is very similar to that in the solid solutions of BiFeO3 with non-magnetic ions, implying the lack of magnetic exchange between Fe3+ and Cr3+. The reason of such behavior seems to be a difference in their electronic configuration. Addition of Cr to PbFe0.5Sb0.5O3 leads to a dramatic lowering and diffusion of the dielectric permittivity maximum and its shift to lower temperatures. Thus, Cr substitution for Fe seems to destroy both ferroelectric and magnetic long-range order in perovskite multiferroics.",

author = "Raevskaya, {S. I.} and Kubrin, {S. P.} and Pushkarev, {A. V.} and Olekhnovich, {N. M.} and Radyush, {Y. V.} and Titov, {V. V.} and Haydn Chen and Chou, {C. C.} and Malitskaya, {M. A.} and Raevski, {I. P.} and Stashenko, {V. V.} and Sarychev, {D. A.}",

year = "2018",

month = jan,

day = "1",

doi = "10.1007/978-3-319-78919-4_16",

language = "English",

isbn = "9783319789187",

series = "Springer Proceedings in Physics",

publisher = "Springer Science and Business Media, LLC",

pages = "195--208",

editor = "Shun-Hsyung Chang and Parinov, {Ivan A.} and Gupta, {Vijay K.}",

booktitle = "Advanced Materials - Proceedings of the International Conference on {"}Physics and Mechanics of New Materials and Their Applications{"}, PHENMA 2017",

note = "International Conference on Physics, Mechanics of New Materials and Their Applications, PHENMA 2017 ; Conference date: 14-10-2017 Through 16-10-2017",

}

Raevskaya, SI, Kubrin, SP, Pushkarev, AV, Olekhnovich, NM, Radyush, YV, Titov, VV, Chen, H, Chou, CC, Malitskaya, MA, Raevski, IP, Stashenko, VV & Sarychev, DA 2018, The effect of cr-doping on the structure, dielectric and magnetic properties of BiFeO₃ and Pb(Fe_0.5Sb_0.5)O₃ multiferroics. in S-H Chang, IA Parinov & VK Gupta (eds), Advanced Materials - Proceedings of the International Conference on "Physics and Mechanics of New Materials and Their Applications", PHENMA 2017. Springer Proceedings in Physics, vol. 207, Springer Science and Business Media, LLC, pp. 195-208, International Conference on Physics, Mechanics of New Materials and Their Applications, PHENMA 2017, Jabalapur, India, 14/10/17. https://doi.org/10.1007/978-3-319-78919-4_16

The effect of cr-doping on the structure, dielectric and magnetic properties of BiFeO₃ and Pb(Fe_0.5Sb_0.5)O₃ multiferroics. / Raevskaya, S. I.; Kubrin, S. P.; Pushkarev, A. V. et al.
Advanced Materials - Proceedings of the International Conference on "Physics and Mechanics of New Materials and Their Applications", PHENMA 2017. ed. / Shun-Hsyung Chang; Ivan A. Parinov; Vijay K. Gupta. Springer Science and Business Media, LLC, 2018. p. 195-208 (Springer Proceedings in Physics; Vol. 207).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

TY - GEN

T1 - The effect of cr-doping on the structure, dielectric and magnetic properties of BiFeO3 and Pb(Fe0.5Sb0.5)O3 multiferroics

AU - Raevskaya, S. I.

AU - Kubrin, S. P.

AU - Pushkarev, A. V.

AU - Olekhnovich, N. M.

AU - Radyush, Y. V.

AU - Titov, V. V.

AU - Chen, Haydn

AU - Chou, C. C.

AU - Malitskaya, M. A.

AU - Raevski, I. P.

AU - Stashenko, V. V.

AU - Sarychev, D. A.

PY - 2018/1/1

Y1 - 2018/1/1

N2 - X-ray diffraction and Mössbauer studies of perovskite BiFe1−xCrxO3 and PbFe0.5−xCrxSb0.5O3 solid solution ceramics, fabricated under high pressure (4–6 GPa) have been carried out. Two morphotropic phase boundaries were revealed in the BiFe1−xCrxO3 system: one between rhombohedral (R3c) and orthorhombic (Pbam) phases at x ≈ 0.5–0.6 and the other between the orthorhombic (Pbam) and monoclinic (C2/c) phases at x ≈ 0.9. It was found out that substitution of Cr3+ for Fe3+ in BiFeO3 does not lead to the appearance of a low-spin state of Fe3+ ions, as was predicted by some first-principles calculations. A composition dependence of the magnetic phase transition temperature for BiFe1−xCrxO3 is very similar to that in the solid solutions of BiFeO3 with non-magnetic ions, implying the lack of magnetic exchange between Fe3+ and Cr3+. The reason of such behavior seems to be a difference in their electronic configuration. Addition of Cr to PbFe0.5Sb0.5O3 leads to a dramatic lowering and diffusion of the dielectric permittivity maximum and its shift to lower temperatures. Thus, Cr substitution for Fe seems to destroy both ferroelectric and magnetic long-range order in perovskite multiferroics.

AB - X-ray diffraction and Mössbauer studies of perovskite BiFe1−xCrxO3 and PbFe0.5−xCrxSb0.5O3 solid solution ceramics, fabricated under high pressure (4–6 GPa) have been carried out. Two morphotropic phase boundaries were revealed in the BiFe1−xCrxO3 system: one between rhombohedral (R3c) and orthorhombic (Pbam) phases at x ≈ 0.5–0.6 and the other between the orthorhombic (Pbam) and monoclinic (C2/c) phases at x ≈ 0.9. It was found out that substitution of Cr3+ for Fe3+ in BiFeO3 does not lead to the appearance of a low-spin state of Fe3+ ions, as was predicted by some first-principles calculations. A composition dependence of the magnetic phase transition temperature for BiFe1−xCrxO3 is very similar to that in the solid solutions of BiFeO3 with non-magnetic ions, implying the lack of magnetic exchange between Fe3+ and Cr3+. The reason of such behavior seems to be a difference in their electronic configuration. Addition of Cr to PbFe0.5Sb0.5O3 leads to a dramatic lowering and diffusion of the dielectric permittivity maximum and its shift to lower temperatures. Thus, Cr substitution for Fe seems to destroy both ferroelectric and magnetic long-range order in perovskite multiferroics.

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U2 - 10.1007/978-3-319-78919-4_16

DO - 10.1007/978-3-319-78919-4_16

M3 - Conference contribution

AN - SCOPUS:85047219499

SN - 9783319789187

T3 - Springer Proceedings in Physics

SP - 195

EP - 208

BT - Advanced Materials - Proceedings of the International Conference on "Physics and Mechanics of New Materials and Their Applications", PHENMA 2017

A2 - Chang, Shun-Hsyung

A2 - Parinov, Ivan A.

A2 - Gupta, Vijay K.

PB - Springer Science and Business Media, LLC

T2 - International Conference on Physics, Mechanics of New Materials and Their Applications, PHENMA 2017

Y2 - 14 October 2017 through 16 October 2017

ER -

Raevskaya SI, Kubrin SP, Pushkarev AV, Olekhnovich NM, Radyush YV, Titov VV et al. The effect of cr-doping on the structure, dielectric and magnetic properties of BiFeO₃ and Pb(Fe_0.5Sb_0.5)O₃ multiferroics. In Chang S-H, Parinov IA, Gupta VK, editors, Advanced Materials - Proceedings of the International Conference on "Physics and Mechanics of New Materials and Their Applications", PHENMA 2017. Springer Science and Business Media, LLC. 2018. p. 195-208. (Springer Proceedings in Physics). doi: 10.1007/978-3-319-78919-4_16