The Combination Reaction of CH3 and C6H5O

Chin Yu Lin; Ming-Chang Lin

doi:10.1071/CH9860723

The Combination Reaction of CH₃ and C₆H₅O

Chin Yu Lin, Ming-Chang Lin

Department of Applied Chemistry

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8 Scopus citations

Abstract

The kinetics and mechanism of the CH₃ + C₆H₅O reaction have been examined by means of the RRKM theory and kinetic modelling. Both the high temperature shock tube data for the production of cresols and the low temperature branching ratios (for production of cresols against methylcyclohexadienones, CH3C₆H₅O) derived from Mulcahy and Williams’s data¹ on the pyrolysis of di-t-butyl peroxide and phenol mixtures could be reasonably accounted for by the mechanism: The energy barrier for the thermal isomerization of CH₃C₆H₅O to cresols was estimated to be - 132 kJ mol^-1.

Original language	English
Pages (from-to)	723-734
Number of pages	12
Journal	Australian Journal of Chemistry
Volume	39
Issue number	5
DOIs	https://doi.org/10.1071/CH9860723
State	Published - 1 Jan 1985

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abstract = "The kinetics and mechanism of the CH3 + C6H5O reaction have been examined by means of the RRKM theory and kinetic modelling. Both the high temperature shock tube data for the production of cresols and the low temperature branching ratios (for production of cresols against methylcyclohexadienones, CH3C6H5O) derived from Mulcahy and Williams{\textquoteright}s data1 on the pyrolysis of di-t-butyl peroxide and phenol mixtures could be reasonably accounted for by the mechanism: The energy barrier for the thermal isomerization of CH3C6H5O to cresols was estimated to be - 132 kJ mol-1.",

author = "Lin, {Chin Yu} and Ming-Chang Lin",

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N2 - The kinetics and mechanism of the CH3 + C6H5O reaction have been examined by means of the RRKM theory and kinetic modelling. Both the high temperature shock tube data for the production of cresols and the low temperature branching ratios (for production of cresols against methylcyclohexadienones, CH3C6H5O) derived from Mulcahy and Williams’s data1 on the pyrolysis of di-t-butyl peroxide and phenol mixtures could be reasonably accounted for by the mechanism: The energy barrier for the thermal isomerization of CH3C6H5O to cresols was estimated to be - 132 kJ mol-1.

AB - The kinetics and mechanism of the CH3 + C6H5O reaction have been examined by means of the RRKM theory and kinetic modelling. Both the high temperature shock tube data for the production of cresols and the low temperature branching ratios (for production of cresols against methylcyclohexadienones, CH3C6H5O) derived from Mulcahy and Williams’s data1 on the pyrolysis of di-t-butyl peroxide and phenol mixtures could be reasonably accounted for by the mechanism: The energy barrier for the thermal isomerization of CH3C6H5O to cresols was estimated to be - 132 kJ mol-1.

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The Combination Reaction of CH₃ and C₆H₅O

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