Synthesis of Aliphatic Amides through a Photoredox Catalyzed Radical Carbonylation Involving Organosilicates as Alkyl Radical Precursors

Alex Cartier, Etienne Levernier, Anne-Lise Dhimane, Takahide Fukuyama, Cyril Ollivier, Ilhyong Ryu, Louis Fensterbank

    Research output: Contribution to journalArticlepeer-review

    16 Scopus citations

    Abstract

    Alkyl radicals, from primary to tertiary, formed by photocatalyzed oxidation of organosilicates, are involved efficiently in radical carbonylation with carbon monoxide (CO), in the presence of various amines and CCl4, leading to a variety of amides in moderate to good yields.

    Original languageEnglish
    Number of pages7
    JournalAdvanced Synthesis and Catalysis
    DOIs
    StateE-pub ahead of print - 8 Apr 2020

    Keywords

    • Carbonylation
    • multi-component reaction
    • photooxidative catalysis
    • radical/polar
    • silicates
    • ATOM-TRANSFER CARBONYLATION
    • ARYLDIAZONIUM SALTS
    • CARBOXYLIC-ACIDS
    • CARBON-MONOXIDE
    • METAL-FREE
    • LIGHT
    • GENERATION
    • SILICATES
    • OXIDATION
    • IODIDES

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