Synthesis of β-mercuri ketones by the reaction of siloxycyclopropanes with mercuric acetate and their conversion to α-methylene ketones and γ-ketoesters

Ilhyong Ryu; Koichi Matsumoto; Masato Ando; Shinji Murai; Noboru Sonoda

doi:10.1016/S0040-4039(00)92884-3

Synthesis of β-mercuri ketones by the reaction of siloxycyclopropanes with mercuric acetate and their conversion to α-methylene ketones and γ-ketoesters

Ilhyong Ryu^*, Koichi Matsumoto, Masato Ando, Shinji Murai, Noboru Sonoda

^*Corresponding author for this work

Department of Applied Chemistry

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61 Scopus citations

Abstract

Siloxycyclopropanes were quantitatively converted to β-acetoxymercuri ketones by the reaction with mercuric acetate. Successive treatment with palladium chloride or palladium chloride/carbon monoxide gave α-methylene ketones or γ-ketoesters, respectively, in good yields.

Original language	English
Pages (from-to)	4283-4286
Number of pages	4
Journal	Tetrahedron Letters
Volume	21
Issue number	44
DOIs	https://doi.org/10.1016/S0040-4039(00)92884-3
State	Published - 1 Jan 1980

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title = "Synthesis of β-mercuri ketones by the reaction of siloxycyclopropanes with mercuric acetate and their conversion to α-methylene ketones and γ-ketoesters",

abstract = "Siloxycyclopropanes were quantitatively converted to β-acetoxymercuri ketones by the reaction with mercuric acetate. Successive treatment with palladium chloride or palladium chloride/carbon monoxide gave α-methylene ketones or γ-ketoesters, respectively, in good yields.",

author = "Ilhyong Ryu and Koichi Matsumoto and Masato Ando and Shinji Murai and Noboru Sonoda",

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T1 - Synthesis of β-mercuri ketones by the reaction of siloxycyclopropanes with mercuric acetate and their conversion to α-methylene ketones and γ-ketoesters

AU - Ryu, Ilhyong

AU - Matsumoto, Koichi

AU - Ando, Masato

AU - Murai, Shinji

AU - Sonoda, Noboru

PY - 1980/1/1

Y1 - 1980/1/1

N2 - Siloxycyclopropanes were quantitatively converted to β-acetoxymercuri ketones by the reaction with mercuric acetate. Successive treatment with palladium chloride or palladium chloride/carbon monoxide gave α-methylene ketones or γ-ketoesters, respectively, in good yields.

AB - Siloxycyclopropanes were quantitatively converted to β-acetoxymercuri ketones by the reaction with mercuric acetate. Successive treatment with palladium chloride or palladium chloride/carbon monoxide gave α-methylene ketones or γ-ketoesters, respectively, in good yields.

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U2 - 10.1016/S0040-4039(00)92884-3

DO - 10.1016/S0040-4039(00)92884-3

M3 - Article

AN - SCOPUS:0000743233

VL - 21

SP - 4283

EP - 4286

JO - Tetrahedron Letters

JF - Tetrahedron Letters

SN - 0040-4039

IS - 44

ER -

Synthesis of β-mercuri ketones by the reaction of siloxycyclopropanes with mercuric acetate and their conversion to α-methylene ketones and γ-ketoesters

Abstract

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