Synthesis, Characterization, and Properties of Ethylene-Coordinated Complexes of β-Platinum(II) Ketones

Kiyoshi Ikura; Ilhyong Ryu; Akiya Ogawa; Noboru Sonoda; Shigeharu Harada; Nobutami Kasai

doi:10.1021/om00049a002

Synthesis, Characterization, and Properties of Ethylene-Coordinated Complexes of β-Platinum(II) Ketones

Kiyoshi Ikura, Ilhyong Ryu^*, Akiya Ogawa, Noboru Sonoda, Shigeharu Harada, Nobutami Kasai

^*Corresponding author for this work

Department of Applied Chemistry

Research output: Contribution to journal › Letter › peer-review

26 Scopus citations

Abstract

The reaction of siloxycyclopropanes 1a,b with Zeise's dimer ([Pt(C₂H₄)CI₂]₂) in CHCI₃ yields ethylene-coordinated β-platinum ketones 2a,b in high yields, respectively. The structure of 2b has been determined by X-ray diffraction methods, showing a chloride-bridged di-meric structure. Treatment of 2a with carbon monoxide gives the monomeric CO complex 3a, which has intramolecular coordination of the carbonyl group.

Original language	English
Pages (from-to)	528-529
Number of pages	2
Journal	Organometallics
Volume	10
Issue number	3
DOIs	https://doi.org/10.1021/om00049a002
State	Published - 27 Mar 1991

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title = "Synthesis, Characterization, and Properties of Ethylene-Coordinated Complexes of β-Platinum(II) Ketones",

abstract = "The reaction of siloxycyclopropanes 1a,b with Zeise's dimer ([Pt(C2H4)CI2]2) in CHCI3 yields ethylene-coordinated β-platinum ketones 2a,b in high yields, respectively. The structure of 2b has been determined by X-ray diffraction methods, showing a chloride-bridged di-meric structure. Treatment of 2a with carbon monoxide gives the monomeric CO complex 3a, which has intramolecular coordination of the carbonyl group.",

author = "Kiyoshi Ikura and Ilhyong Ryu and Akiya Ogawa and Noboru Sonoda and Shigeharu Harada and Nobutami Kasai",

year = "1991",

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T1 - Synthesis, Characterization, and Properties of Ethylene-Coordinated Complexes of β-Platinum(II) Ketones

AU - Ikura, Kiyoshi

AU - Ryu, Ilhyong

AU - Ogawa, Akiya

AU - Sonoda, Noboru

AU - Harada, Shigeharu

AU - Kasai, Nobutami

PY - 1991/3/27

Y1 - 1991/3/27

N2 - The reaction of siloxycyclopropanes 1a,b with Zeise's dimer ([Pt(C2H4)CI2]2) in CHCI3 yields ethylene-coordinated β-platinum ketones 2a,b in high yields, respectively. The structure of 2b has been determined by X-ray diffraction methods, showing a chloride-bridged di-meric structure. Treatment of 2a with carbon monoxide gives the monomeric CO complex 3a, which has intramolecular coordination of the carbonyl group.

AB - The reaction of siloxycyclopropanes 1a,b with Zeise's dimer ([Pt(C2H4)CI2]2) in CHCI3 yields ethylene-coordinated β-platinum ketones 2a,b in high yields, respectively. The structure of 2b has been determined by X-ray diffraction methods, showing a chloride-bridged di-meric structure. Treatment of 2a with carbon monoxide gives the monomeric CO complex 3a, which has intramolecular coordination of the carbonyl group.

UR - http://www.scopus.com/inward/record.url?scp=0001550452&partnerID=8YFLogxK

U2 - 10.1021/om00049a002

DO - 10.1021/om00049a002

M3 - Letter

AN - SCOPUS:0001550452

SN - 0276-7333

VL - 10

SP - 528

EP - 529

JO - Organometallics

JF - Organometallics

IS - 3

ER -

Synthesis, Characterization, and Properties of Ethylene-Coordinated Complexes of β-Platinum(II) Ketones

Abstract

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