Studies of ferroelectric and magnetic phase transitions in multiferroic PbFe0.5B0.5O3–PbTiO3 (B = Nb, Ta) solid solution ceramics

I. P. Raevski; S. P. Kubrin; A. V. Blazhevich; M. S. Molokeev; S. V. Misjul; E. V. Eremin; Haydn Chen; C. C. Chou; E. I. Sitalo; S. I. Raevskaya; V. V. Titov; D. A. Sarychev; M. A. Malitskaya; I. N. Zakharchenko

doi:10.1007/978-3-319-03749-3_9

Studies of ferroelectric and magnetic phase transitions in multiferroic PbFe_0.5B_0.5O₃–PbTiO₃ (B = Nb, Ta) solid solution ceramics

I. P. Raevski, S. P. Kubrin, A. V. Blazhevich, M. S. Molokeev, S. V. Misjul, E. V. Eremin, Haydn Chen, C. C. Chou, E. I. Sitalo, S. I. Raevskaya^*, V. V. Titov, D. A. Sarychev, M. A. Malitskaya, I. N. Zakharchenko

^*Corresponding author for this work

International College of Semiconductor Technology

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

2 Scopus citations

Abstract

Dielectric, X-ray, Mössbauer and magnetization studies of (1-x)PbFe_0.5B_0.5O₃– (x)PbTiO₃ (B = Nb, Ta) ceramics from the 0 < x < 0.3 range have been carried out. Addition of PbTiO₃ to PbFe_0.5B_0.5O₃ increases the temperature T_m of the permittivity maximum, decreases the diffusion of this maximum and lowers the Neél temperature T_N. However above a certain compositional threshold (x ≈ 0.1) fast lowering of T_N stops and a new magnetic state stable in a rather wide compositional range appears. Large difference between the zero-field cooled and fieldcooled magnetization-temperature curves as well as between the temperatures of magnetic phase transition determined from Mössbauer and magnetization studies for compositions with x > 0.1 implies that this state is a spin glass phase.

Original language	English
Title of host publication	Advanced Materials - Physics, Mechanics and Applications
Editors	Shun-Hsyung Chang, Ivan A. Parinov, Vitaly Yu. Topolov
Publisher	Springer Science and Business Media, LLC
Pages	109-120
Number of pages	12
ISBN (Electronic)	9783319037486
DOIs	https://doi.org/10.1007/978-3-319-03749-3_9
State	Published - 1 Jan 2014
Event	International Symposium on Physics and Mechanics of New Materials and Underwater Applications, PHENMA 2013 - Kaohsiung, Taiwan Duration: 5 Jun 2013 → 8 Jun 2013

Publication series

Name	Springer Proceedings in Physics
Volume	152
ISSN (Print)	0930-8989
ISSN (Electronic)	1867-4941

Conference

Conference	International Symposium on Physics and Mechanics of New Materials and Underwater Applications, PHENMA 2013
Country/Territory	Taiwan
City	Kaohsiung
Period	5/06/13 → 8/06/13

Access to Document

10.1007/978-3-319-03749-3_9

Cite this

Raevski, I. P., Kubrin, S. P., Blazhevich, A. V., Molokeev, M. S., Misjul, S. V., Eremin, E. V., Chen, H., Chou, C. C., Sitalo, E. I., Raevskaya, S. I., Titov, V. V., Sarychev, D. A., Malitskaya, M. A., & Zakharchenko, I. N. (2014). Studies of ferroelectric and magnetic phase transitions in multiferroic PbFe_0.5B_0.5O₃–PbTiO₃ (B = Nb, Ta) solid solution ceramics. In S-H. Chang, I. A. Parinov, & V. Y. Topolov (Eds.), Advanced Materials - Physics, Mechanics and Applications (pp. 109-120). (Springer Proceedings in Physics; Vol. 152). Springer Science and Business Media, LLC. https://doi.org/10.1007/978-3-319-03749-3_9

Raevski, I. P. ; Kubrin, S. P. ; Blazhevich, A. V. et al. / Studies of ferroelectric and magnetic phase transitions in multiferroic PbFe_0.5B_0.5O₃–PbTiO₃ (B = Nb, Ta) solid solution ceramics. Advanced Materials - Physics, Mechanics and Applications. editor / Shun-Hsyung Chang ; Ivan A. Parinov ; Vitaly Yu. Topolov. Springer Science and Business Media, LLC, 2014. pp. 109-120 (Springer Proceedings in Physics).

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title = "Studies of ferroelectric and magnetic phase transitions in multiferroic PbFe0.5B0.5O3–PbTiO3 (B = Nb, Ta) solid solution ceramics",

abstract = "Dielectric, X-ray, M{\"o}ssbauer and magnetization studies of (1-x)PbFe0.5B0.5O3– (x)PbTiO3 (B = Nb, Ta) ceramics from the 0 < x < 0.3 range have been carried out. Addition of PbTiO3 to PbFe0.5B0.5O3 increases the temperature Tm of the permittivity maximum, decreases the diffusion of this maximum and lowers the Ne{\'e}l temperature TN. However above a certain compositional threshold (x ≈ 0.1) fast lowering of TN stops and a new magnetic state stable in a rather wide compositional range appears. Large difference between the zero-field cooled and fieldcooled magnetization-temperature curves as well as between the temperatures of magnetic phase transition determined from M{\"o}ssbauer and magnetization studies for compositions with x > 0.1 implies that this state is a spin glass phase.",

author = "Raevski, {I. P.} and Kubrin, {S. P.} and Blazhevich, {A. V.} and Molokeev, {M. S.} and Misjul, {S. V.} and Eremin, {E. V.} and Haydn Chen and Chou, {C. C.} and Sitalo, {E. I.} and Raevskaya, {S. I.} and Titov, {V. V.} and Sarychev, {D. A.} and Malitskaya, {M. A.} and Zakharchenko, {I. N.}",

year = "2014",

month = jan,

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doi = "10.1007/978-3-319-03749-3_9",

language = "English",

series = "Springer Proceedings in Physics",

publisher = "Springer Science and Business Media, LLC",

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editor = "Shun-Hsyung Chang and Parinov, {Ivan A.} and Topolov, {Vitaly Yu.}",

booktitle = "Advanced Materials - Physics, Mechanics and Applications",

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Raevski, IP, Kubrin, SP, Blazhevich, AV, Molokeev, MS, Misjul, SV, Eremin, EV, Chen, H, Chou, CC, Sitalo, EI, Raevskaya, SI, Titov, VV, Sarychev, DA, Malitskaya, MA & Zakharchenko, IN 2014, Studies of ferroelectric and magnetic phase transitions in multiferroic PbFe_0.5B_0.5O₃–PbTiO₃ (B = Nb, Ta) solid solution ceramics. in S-H Chang, IA Parinov & VY Topolov (eds), Advanced Materials - Physics, Mechanics and Applications. Springer Proceedings in Physics, vol. 152, Springer Science and Business Media, LLC, pp. 109-120, International Symposium on Physics and Mechanics of New Materials and Underwater Applications, PHENMA 2013, Kaohsiung, Taiwan, 5/06/13. https://doi.org/10.1007/978-3-319-03749-3_9

Studies of ferroelectric and magnetic phase transitions in multiferroic PbFe_0.5B_0.5O₃–PbTiO₃ (B = Nb, Ta) solid solution ceramics. / Raevski, I. P.; Kubrin, S. P.; Blazhevich, A. V. et al.
Advanced Materials - Physics, Mechanics and Applications. ed. / Shun-Hsyung Chang; Ivan A. Parinov; Vitaly Yu. Topolov. Springer Science and Business Media, LLC, 2014. p. 109-120 (Springer Proceedings in Physics; Vol. 152).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

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AU - Blazhevich, A. V.

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AU - Eremin, E. V.

AU - Chen, Haydn

AU - Chou, C. C.

AU - Sitalo, E. I.

AU - Raevskaya, S. I.

AU - Titov, V. V.

AU - Sarychev, D. A.

AU - Malitskaya, M. A.

AU - Zakharchenko, I. N.

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N2 - Dielectric, X-ray, Mössbauer and magnetization studies of (1-x)PbFe0.5B0.5O3– (x)PbTiO3 (B = Nb, Ta) ceramics from the 0 < x < 0.3 range have been carried out. Addition of PbTiO3 to PbFe0.5B0.5O3 increases the temperature Tm of the permittivity maximum, decreases the diffusion of this maximum and lowers the Neél temperature TN. However above a certain compositional threshold (x ≈ 0.1) fast lowering of TN stops and a new magnetic state stable in a rather wide compositional range appears. Large difference between the zero-field cooled and fieldcooled magnetization-temperature curves as well as between the temperatures of magnetic phase transition determined from Mössbauer and magnetization studies for compositions with x > 0.1 implies that this state is a spin glass phase.

AB - Dielectric, X-ray, Mössbauer and magnetization studies of (1-x)PbFe0.5B0.5O3– (x)PbTiO3 (B = Nb, Ta) ceramics from the 0 < x < 0.3 range have been carried out. Addition of PbTiO3 to PbFe0.5B0.5O3 increases the temperature Tm of the permittivity maximum, decreases the diffusion of this maximum and lowers the Neél temperature TN. However above a certain compositional threshold (x ≈ 0.1) fast lowering of TN stops and a new magnetic state stable in a rather wide compositional range appears. Large difference between the zero-field cooled and fieldcooled magnetization-temperature curves as well as between the temperatures of magnetic phase transition determined from Mössbauer and magnetization studies for compositions with x > 0.1 implies that this state is a spin glass phase.

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T3 - Springer Proceedings in Physics

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BT - Advanced Materials - Physics, Mechanics and Applications

A2 - Chang, Shun-Hsyung

A2 - Parinov, Ivan A.

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Raevski IP, Kubrin SP, Blazhevich AV, Molokeev MS, Misjul SV, Eremin EV et al. Studies of ferroelectric and magnetic phase transitions in multiferroic PbFe_0.5B_0.5O₃–PbTiO₃ (B = Nb, Ta) solid solution ceramics. In Chang S-H, Parinov IA, Topolov VY, editors, Advanced Materials - Physics, Mechanics and Applications. Springer Science and Business Media, LLC. 2014. p. 109-120. (Springer Proceedings in Physics). doi: 10.1007/978-3-319-03749-3_9