Site-Selective C(sp3)-H Alkenylation Using Decatungstate Anion as Photocatalyst

Yi Ting Wang, Yi Lun Shih, Yen Ku Wu, Ilhyong Ryu*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

1 Scopus citations

Abstract

Site-selective C(sp3)-H alkenylation was achieved under photo-irradiation in the presence of a catalytic amount of decatungstate anion, W10O324−. In this reaction, the radical addition/β-scission sequence is successfully combined with photocatalytic C(sp3)-H functionalization. The reaction using weaker C−H bonds such as those in THF revealed that the benzenesulfonyl radical itself underwent HAT directly from the C−H bond, and a decatungstate anion participated in a chain-repairing step. (Figure presented.).

Original languageEnglish
Pages (from-to)1039-1043
Number of pages5
JournalAdvanced Synthesis and Catalysis
Volume364
Issue number5
DOIs
StatePublished - 1 Mar 2022

Keywords

  • 1,2-bis(sulfonyl)ethylene
  • C(sp)-H alkenylation
  • benzenesulfonyl radical
  • decatungstate anion
  • photocatalyst

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