TY - JOUR
T1 - Shape-Tunable SrTiO3 Crystals Revealing Facet-Dependent Optical and Photocatalytic Properties
AU - Hsieh, Pei Lun
AU - Naresh, Gollapally
AU - Huang, Yu Sheng
AU - Tsao, Chun Wen
AU - Hsu, Yung-Jung
AU - Chen, Lih Juann
AU - Huang, Michael H.
PY - 2019/6/6
Y1 - 2019/6/6
N2 - SrTiO3 cubes with tunable sizes of 160-290 nm have been synthesized by mixing TiCl4, SrCl2, and LiOH in pure ethanol or a water/ethanol mixed solution at just 70 °C for 3 h. Replacing water/ethanol with water/hexanol and water/ethylene glycol, and fine tuning the amounts of other reagents, resulted in the formation of edge-truncated cubes and {100}-truncated rhombic dodecahedra, respectively. X-ray diffraction and transmission electron microscopy characterization, supported by Rietveld refinement analysis, have revealed shape-dependent tuning in lattice parameters. The cubes display slight size-related optical band shifts, and they show clearly more blue-shifted light absorption than the other particles exposing significant {110} faces. The {100}-truncated rhombic dodecahedra are far more efficient than cubes at photodegradation of methylene blue and photocatalyzed hydrogen evolution from water in the presence of methanol. The photocatalytic activity variation should arise from different degrees of surface band bending for the {100} and {110} faces of SrTiO3, suggesting surface facet control as a strategy for enhancing photocatalyzed hydrogen production.
AB - SrTiO3 cubes with tunable sizes of 160-290 nm have been synthesized by mixing TiCl4, SrCl2, and LiOH in pure ethanol or a water/ethanol mixed solution at just 70 °C for 3 h. Replacing water/ethanol with water/hexanol and water/ethylene glycol, and fine tuning the amounts of other reagents, resulted in the formation of edge-truncated cubes and {100}-truncated rhombic dodecahedra, respectively. X-ray diffraction and transmission electron microscopy characterization, supported by Rietveld refinement analysis, have revealed shape-dependent tuning in lattice parameters. The cubes display slight size-related optical band shifts, and they show clearly more blue-shifted light absorption than the other particles exposing significant {110} faces. The {100}-truncated rhombic dodecahedra are far more efficient than cubes at photodegradation of methylene blue and photocatalyzed hydrogen evolution from water in the presence of methanol. The photocatalytic activity variation should arise from different degrees of surface band bending for the {100} and {110} faces of SrTiO3, suggesting surface facet control as a strategy for enhancing photocatalyzed hydrogen production.
UR - http://www.scopus.com/inward/record.url?scp=85066453856&partnerID=8YFLogxK
U2 - 10.1021/acs.jpcc.9b02081
DO - 10.1021/acs.jpcc.9b02081
M3 - Article
AN - SCOPUS:85066453856
SN - 1932-7447
VL - 123
SP - 13664
EP - 13671
JO - Journal of Physical Chemistry C
JF - Journal of Physical Chemistry C
IS - 22
ER -
