Rhodium(I)-catalyzed isomerization of siloxycyclopropanes leading to enol silyl ethers and allyl silyl ethers

Kiyoshi Ikura*, Ilhyong Ryu, Akiya Ogawa, Nobuaki Kambe, Noboru Sonoda

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

19 Scopus citations

Abstract

The isomerization of siloxycyclopropanes to enol silyl ethers and allyl silyl ethers was accomplished by using [Rh(CO)2Cl]2 as a catalyst. Regiochemistry with respect to the newly formed double bond of the product was highly dependent on the substitution pattern of cyclopropane ring.

Original languageEnglish
Pages (from-to)6887-6890
Number of pages4
JournalTetrahedron Letters
Volume30
Issue number49
DOIs
StatePublished - 1 Jan 1989

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