Revisiting the synthesis of bis(2-hydroxy-3,5-di-t-butylphenyl)methanone

Xin Jie Lin; Shih Peng Huang; Min Jie Huang; Chien Lung Wang; Chi How Peng; Hsueh Ju Liu; Yen Ku Wu

doi:10.1002/jccs.202200358

Revisiting the synthesis of bis(2-hydroxy-3,5-di-t-butylphenyl)methanone

Xin Jie Lin, Shih Peng Huang, Min Jie Huang, Chien Lung Wang, Chi How Peng^*, Hsueh Ju Liu^*, Yen Ku Wu^*

^*Corresponding author for this work

Department of Applied Chemistry

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

Described is our effort toward establishing a practical and sustainable synthesis of bis(2-hydroxy-3,5-di-t-butylphenyl)methanone. In it, we found the phenol-aldehyde condensation could be efficiently catalyzed by sulfonic acid-functionalized microporous carbon spheres (MCS-SO₃H). Additionally, we developed practical and sustainable procedures for the synthesis of the title ligand by applying readily available reagents in lieu of toxic chromium trioxide and fuming boron tribromide.

Original language	English
Pages (from-to)	1803-1809
Number of pages	7
Journal	Journal of the Chinese Chemical Society
Volume	69
Issue number	10
DOIs	https://doi.org/10.1002/jccs.202200358
State	Published - Oct 2022

Keywords

hydroxybenzophenone
oxygen donor ligand
persulfate
solid acid catalyst
xanthone

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title = "Revisiting the synthesis of bis(2-hydroxy-3,5-di-t-butylphenyl)methanone",

abstract = "Described is our effort toward establishing a practical and sustainable synthesis of bis(2-hydroxy-3,5-di-t-butylphenyl)methanone. In it, we found the phenol-aldehyde condensation could be efficiently catalyzed by sulfonic acid-functionalized microporous carbon spheres (MCS-SO3H). Additionally, we developed practical and sustainable procedures for the synthesis of the title ligand by applying readily available reagents in lieu of toxic chromium trioxide and fuming boron tribromide.",

keywords = "hydroxybenzophenone, oxygen donor ligand, persulfate, solid acid catalyst, xanthone",

author = "Lin, {Xin Jie} and Huang, {Shih Peng} and Huang, {Min Jie} and Wang, {Chien Lung} and Peng, {Chi How} and Liu, {Hsueh Ju} and Wu, {Yen Ku}",

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AU - Lin, Xin Jie

AU - Huang, Shih Peng

AU - Huang, Min Jie

AU - Wang, Chien Lung

AU - Peng, Chi How

AU - Liu, Hsueh Ju

AU - Wu, Yen Ku

PY - 2022/10

Y1 - 2022/10

N2 - Described is our effort toward establishing a practical and sustainable synthesis of bis(2-hydroxy-3,5-di-t-butylphenyl)methanone. In it, we found the phenol-aldehyde condensation could be efficiently catalyzed by sulfonic acid-functionalized microporous carbon spheres (MCS-SO3H). Additionally, we developed practical and sustainable procedures for the synthesis of the title ligand by applying readily available reagents in lieu of toxic chromium trioxide and fuming boron tribromide.

AB - Described is our effort toward establishing a practical and sustainable synthesis of bis(2-hydroxy-3,5-di-t-butylphenyl)methanone. In it, we found the phenol-aldehyde condensation could be efficiently catalyzed by sulfonic acid-functionalized microporous carbon spheres (MCS-SO3H). Additionally, we developed practical and sustainable procedures for the synthesis of the title ligand by applying readily available reagents in lieu of toxic chromium trioxide and fuming boron tribromide.

KW - hydroxybenzophenone

KW - oxygen donor ligand

KW - persulfate

KW - solid acid catalyst

KW - xanthone

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JO - Journal of the Chinese Chemical Society

JF - Journal of the Chinese Chemical Society

IS - 10

ER -

Revisiting the synthesis of bis(2-hydroxy-3,5-di-t-butylphenyl)methanone

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Keywords

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