Resonant x-ray emission spectroscopy of multiferroic TbMnO 3

J. M. Chen; C. K. Chen; T. L. Chou; I. Jarrige; H. Ishii; K. T. Lu; Y. Q. Cai; K. S. Liang; J. M. Lee; S. W. Huang; T. J. Yang; C. C. Shen; R. S. Liu; Jiunn-Yuan Lin; H. T. Jeng; C. C. Kao

doi:10.1063/1.2762288

Resonant x-ray emission spectroscopy of multiferroic TbMnO ₃

J. M. Chen^*, C. K. Chen, T. L. Chou, I. Jarrige, H. Ishii, K. T. Lu, Y. Q. Cai, K. S. Liang, J. M. Lee, S. W. Huang, T. J. Yang, C. C. Shen, R. S. Liu, Jiunn-Yuan Lin, H. T. Jeng, C. C. Kao

^*Corresponding author for this work

Institute of Physics

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

The Mn 3d valence states in single-crystalline TbMn O3 were probed using x-ray absorption spectroscopy and resonant x-ray emission spectroscopy (RXES). The polarized Mn K -edge x-ray absorption spectra show a strong polarization dependence, particularly for the white line region, indicating the strong anisotropic Mn-O bonding within the ab plane in TbMn O3. The RXES data obtained at the Mn K edge clearly reveal that unoccupied Mn 3d states exhibit a relatively delocalized character, stemming from hybridization of the Mn 3d states with the neighboring Mn 4p orbitals. The authors demonstrated that resonant x-ray emission spectroscopy is able to characterize the degree of localization of the unoccupied states or hole carriers in manganites.

Original language	English
Article number	054108
Journal	Applied Physics Letters
Volume	91
Issue number	5
DOIs	https://doi.org/10.1063/1.2762288
State	Published - 30 Jul 2007

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@article{59670c505ade410eb0236b171cf9e887,

title = "Resonant x-ray emission spectroscopy of multiferroic TbMnO 3",

abstract = "The Mn 3d valence states in single-crystalline TbMn O3 were probed using x-ray absorption spectroscopy and resonant x-ray emission spectroscopy (RXES). The polarized Mn K -edge x-ray absorption spectra show a strong polarization dependence, particularly for the white line region, indicating the strong anisotropic Mn-O bonding within the ab plane in TbMn O3. The RXES data obtained at the Mn K edge clearly reveal that unoccupied Mn 3d states exhibit a relatively delocalized character, stemming from hybridization of the Mn 3d states with the neighboring Mn 4p orbitals. The authors demonstrated that resonant x-ray emission spectroscopy is able to characterize the degree of localization of the unoccupied states or hole carriers in manganites.",

author = "Chen, {J. M.} and Chen, {C. K.} and Chou, {T. L.} and I. Jarrige and H. Ishii and Lu, {K. T.} and Cai, {Y. Q.} and Liang, {K. S.} and Lee, {J. M.} and Huang, {S. W.} and Yang, {T. J.} and Shen, {C. C.} and Liu, {R. S.} and Jiunn-Yuan Lin and Jeng, {H. T.} and Kao, {C. C.}",

year = "2007",

month = jul,

day = "30",

doi = "10.1063/1.2762288",

language = "English",

volume = "91",

journal = "Applied Physics Letters",

issn = "0003-6951",

publisher = "American Institute of Physics",

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TY - JOUR

T1 - Resonant x-ray emission spectroscopy of multiferroic TbMnO 3

AU - Chen, J. M.

AU - Chen, C. K.

AU - Chou, T. L.

AU - Jarrige, I.

AU - Ishii, H.

AU - Lu, K. T.

AU - Cai, Y. Q.

AU - Liang, K. S.

AU - Lee, J. M.

AU - Huang, S. W.

AU - Yang, T. J.

AU - Shen, C. C.

AU - Liu, R. S.

AU - Lin, Jiunn-Yuan

AU - Jeng, H. T.

AU - Kao, C. C.

PY - 2007/7/30

Y1 - 2007/7/30

N2 - The Mn 3d valence states in single-crystalline TbMn O3 were probed using x-ray absorption spectroscopy and resonant x-ray emission spectroscopy (RXES). The polarized Mn K -edge x-ray absorption spectra show a strong polarization dependence, particularly for the white line region, indicating the strong anisotropic Mn-O bonding within the ab plane in TbMn O3. The RXES data obtained at the Mn K edge clearly reveal that unoccupied Mn 3d states exhibit a relatively delocalized character, stemming from hybridization of the Mn 3d states with the neighboring Mn 4p orbitals. The authors demonstrated that resonant x-ray emission spectroscopy is able to characterize the degree of localization of the unoccupied states or hole carriers in manganites.

AB - The Mn 3d valence states in single-crystalline TbMn O3 were probed using x-ray absorption spectroscopy and resonant x-ray emission spectroscopy (RXES). The polarized Mn K -edge x-ray absorption spectra show a strong polarization dependence, particularly for the white line region, indicating the strong anisotropic Mn-O bonding within the ab plane in TbMn O3. The RXES data obtained at the Mn K edge clearly reveal that unoccupied Mn 3d states exhibit a relatively delocalized character, stemming from hybridization of the Mn 3d states with the neighboring Mn 4p orbitals. The authors demonstrated that resonant x-ray emission spectroscopy is able to characterize the degree of localization of the unoccupied states or hole carriers in manganites.

UR - http://www.scopus.com/inward/record.url?scp=34547650528&partnerID=8YFLogxK

U2 - 10.1063/1.2762288

DO - 10.1063/1.2762288

M3 - Article

AN - SCOPUS:34547650528

SN - 0003-6951

VL - 91

JO - Applied Physics Letters

JF - Applied Physics Letters

IS - 5

M1 - 054108

ER -

Resonant x-ray emission spectroscopy of multiferroic TbMnO ₃

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