Nanostructure and hydrogen spillover of bridged metal-organic frameworks

Cheng Si Tsao; Ming Sheng Yu; Cheng-Yu Wang; Pin Yen Liao; Hsin Lung Chen; U. Ser Jeng; Yi Ren Tzeng; Tsui Yun Chung; Hsiu Chu Wu

doi:10.1021/ja802741b

Nanostructure and hydrogen spillover of bridged metal-organic frameworks

Cheng Si Tsao^*, Ming Sheng Yu, Cheng-Yu Wang, Pin Yen Liao, Hsin Lung Chen, U. Ser Jeng, Yi Ren Tzeng, Tsui Yun Chung, Hsiu Chu Wu

^*Corresponding author for this work

Department of Materials Science and Engineering

Research output: Contribution to journal › Article › peer-review

101 Scopus citations

Abstract

The metal-organic frameworks (MOF) with low and medium specific surface areas (SSA) were shown to be able to adsorb hydrogen via bridged spillover at room temperature (RT) up to an amount of full coverage of hydrogen in the MOF. Anomalous small-angle X-ray scattering was employed to investigate the key relationship between the structures and storage properties of the involved materials. It was found that the tunable imperfect lattice defects and the 3D pore network in the MOF crystal are the most critical structures for RT hydrogen uptake rather than the known micropores in the crystal, SSA, and Pt catalyst structure.

Original language	English
Pages (from-to)	1404-1406
Number of pages	3
Journal	Journal of the American Chemical Society
Volume	131
Issue number	4
DOIs	https://doi.org/10.1021/ja802741b
State	Published - 4 Feb 2009

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title = "Nanostructure and hydrogen spillover of bridged metal-organic frameworks",

abstract = "The metal-organic frameworks (MOF) with low and medium specific surface areas (SSA) were shown to be able to adsorb hydrogen via bridged spillover at room temperature (RT) up to an amount of full coverage of hydrogen in the MOF. Anomalous small-angle X-ray scattering was employed to investigate the key relationship between the structures and storage properties of the involved materials. It was found that the tunable imperfect lattice defects and the 3D pore network in the MOF crystal are the most critical structures for RT hydrogen uptake rather than the known micropores in the crystal, SSA, and Pt catalyst structure.",

author = "Tsao, {Cheng Si} and Yu, {Ming Sheng} and Cheng-Yu Wang and Liao, {Pin Yen} and Chen, {Hsin Lung} and Jeng, {U. Ser} and Tzeng, {Yi Ren} and Chung, {Tsui Yun} and Wu, {Hsiu Chu}",

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T1 - Nanostructure and hydrogen spillover of bridged metal-organic frameworks

AU - Tsao, Cheng Si

AU - Yu, Ming Sheng

AU - Wang, Cheng-Yu

AU - Liao, Pin Yen

AU - Chen, Hsin Lung

AU - Jeng, U. Ser

AU - Tzeng, Yi Ren

AU - Chung, Tsui Yun

AU - Wu, Hsiu Chu

PY - 2009/2/4

Y1 - 2009/2/4

N2 - The metal-organic frameworks (MOF) with low and medium specific surface areas (SSA) were shown to be able to adsorb hydrogen via bridged spillover at room temperature (RT) up to an amount of full coverage of hydrogen in the MOF. Anomalous small-angle X-ray scattering was employed to investigate the key relationship between the structures and storage properties of the involved materials. It was found that the tunable imperfect lattice defects and the 3D pore network in the MOF crystal are the most critical structures for RT hydrogen uptake rather than the known micropores in the crystal, SSA, and Pt catalyst structure.

AB - The metal-organic frameworks (MOF) with low and medium specific surface areas (SSA) were shown to be able to adsorb hydrogen via bridged spillover at room temperature (RT) up to an amount of full coverage of hydrogen in the MOF. Anomalous small-angle X-ray scattering was employed to investigate the key relationship between the structures and storage properties of the involved materials. It was found that the tunable imperfect lattice defects and the 3D pore network in the MOF crystal are the most critical structures for RT hydrogen uptake rather than the known micropores in the crystal, SSA, and Pt catalyst structure.

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SP - 1404

EP - 1406

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 4

ER -

Nanostructure and hydrogen spillover of bridged metal-organic frameworks

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