Mössbauer study of the effect of mechanical activation on the magnetic properties of PbFe0.5Nb0.5O3

S. P. Kubrin; I. P. Raevski; V. V. Stashenko; A. A. Gusev; V. P. Isupov; H. D. Chen; C. C. Chou; D. A. Sarychev; V. V. Titov; S. I. Raevskaya

doi:10.1007/978-3-319-56062-5_14

Mössbauer study of the effect of mechanical activation on the magnetic properties of PbFe_0.5Nb_0.5O₃

S. P. Kubrin, I. P. Raevski^*, V. V. Stashenko, A. A. Gusev, V. P. Isupov, H. D. Chen, C. C. Chou, D. A. Sarychev, V. V. Titov, S. I. Raevskaya

^*Corresponding author for this work

International College of Semiconductor Technology

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

Abstract

Mössbauer studies of PbFe_0.5Nb_0.5O₃ samples prepared by mechanical activation of PbO, Fe₂O₃ and Nb₂O₅ mixture and subsequent sintering at various temperatures T_S were performed. The room temperature Mössbauer spectra consist of two doublets (D1 and D2) for the samples with T_S < 800 °C and one doublet (D1) for the samples with T_S > 800 °C. The parameters of the doublet D1 correspond to Fe³⁺ in the octahedron environment. Doublet D2 has a lower isomer shift corresponding to Fe³⁺ with the coordination number 5 that indicates the presence of oxygen vacancies. Dependence of the temperature T_N of magnetic phase transition on T_S has a maximum at T_S ≈ 700 °C. The effect of Fe³⁺/Nb⁵⁺ ordering degree and oxygen deficiency on T_N is discussed.

Original language	English
Title of host publication	Advanced Materials - Techniques, Physics, Mechanics and Applications
Editors	Muaffaq A. Jani, Ivan A. Parinov, Shun-Hsyung Chang
Publisher	Springer Science and Business Media, LLC
Pages	155-165
Number of pages	11
ISBN (Print)	9783319560618
DOIs	https://doi.org/10.1007/978-3-319-56062-5_14
State	Published - 1 Jan 2017
Event	International Conference on Physics, Mechanics of New Materials and Their Applications, PHENMA 2016 - Surabaya, Indonesia Duration: 19 Jul 2016 → 22 Jul 2016

Publication series

Name	Springer Proceedings in Physics
Volume	193
ISSN (Print)	0930-8989
ISSN (Electronic)	1867-4941

Conference

Conference	International Conference on Physics, Mechanics of New Materials and Their Applications, PHENMA 2016
Country/Territory	Indonesia
City	Surabaya
Period	19/07/16 → 22/07/16

Access to Document

10.1007/978-3-319-56062-5_14

Cite this

Kubrin, S. P., Raevski, I. P., Stashenko, V. V., Gusev, A. A., Isupov, V. P., Chen, H. D., Chou, C. C., Sarychev, D. A., Titov, V. V., & Raevskaya, S. I. (2017). Mössbauer study of the effect of mechanical activation on the magnetic properties of PbFe_0.5Nb_0.5O₃. In M. A. Jani, I. A. Parinov, & S.-H. Chang (Eds.), Advanced Materials - Techniques, Physics, Mechanics and Applications (pp. 155-165). (Springer Proceedings in Physics; Vol. 193). Springer Science and Business Media, LLC. https://doi.org/10.1007/978-3-319-56062-5_14

Kubrin, S. P. ; Raevski, I. P. ; Stashenko, V. V. et al. / Mössbauer study of the effect of mechanical activation on the magnetic properties of PbFe_0.5Nb_0.5O₃. Advanced Materials - Techniques, Physics, Mechanics and Applications. editor / Muaffaq A. Jani ; Ivan A. Parinov ; Shun-Hsyung Chang. Springer Science and Business Media, LLC, 2017. pp. 155-165 (Springer Proceedings in Physics).

@inproceedings{94c38c34f4f94da1b30de1f8918931c0,

title = "M{\"o}ssbauer study of the effect of mechanical activation on the magnetic properties of PbFe0.5Nb0.5O3",

abstract = "M{\"o}ssbauer studies of PbFe0.5Nb0.5O3 samples prepared by mechanical activation of PbO, Fe2O3 and Nb2O5 mixture and subsequent sintering at various temperatures TS were performed. The room temperature M{\"o}ssbauer spectra consist of two doublets (D1 and D2) for the samples with TS < 800 °C and one doublet (D1) for the samples with TS > 800 °C. The parameters of the doublet D1 correspond to Fe3+ in the octahedron environment. Doublet D2 has a lower isomer shift corresponding to Fe3+ with the coordination number 5 that indicates the presence of oxygen vacancies. Dependence of the temperature TN of magnetic phase transition on TS has a maximum at TS ≈ 700 °C. The effect of Fe3+/Nb5+ ordering degree and oxygen deficiency on TN is discussed.",

author = "Kubrin, {S. P.} and Raevski, {I. P.} and Stashenko, {V. V.} and Gusev, {A. A.} and Isupov, {V. P.} and Chen, {H. D.} and Chou, {C. C.} and Sarychev, {D. A.} and Titov, {V. V.} and Raevskaya, {S. I.}",

year = "2017",

month = jan,

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doi = "10.1007/978-3-319-56062-5_14",

language = "English",

isbn = "9783319560618",

series = "Springer Proceedings in Physics",

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editor = "Jani, {Muaffaq A.} and Parinov, {Ivan A.} and Shun-Hsyung Chang",

booktitle = "Advanced Materials - Techniques, Physics, Mechanics and Applications",

note = "International Conference on Physics, Mechanics of New Materials and Their Applications, PHENMA 2016 ; Conference date: 19-07-2016 Through 22-07-2016",

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Kubrin, SP, Raevski, IP, Stashenko, VV, Gusev, AA, Isupov, VP, Chen, HD, Chou, CC, Sarychev, DA, Titov, VV & Raevskaya, SI 2017, Mössbauer study of the effect of mechanical activation on the magnetic properties of PbFe_0.5Nb_0.5O₃. in MA Jani, IA Parinov & S-H Chang (eds), Advanced Materials - Techniques, Physics, Mechanics and Applications. Springer Proceedings in Physics, vol. 193, Springer Science and Business Media, LLC, pp. 155-165, International Conference on Physics, Mechanics of New Materials and Their Applications, PHENMA 2016, Surabaya, Indonesia, 19/07/16. https://doi.org/10.1007/978-3-319-56062-5_14

Mössbauer study of the effect of mechanical activation on the magnetic properties of PbFe_0.5Nb_0.5O₃. / Kubrin, S. P.; Raevski, I. P.; Stashenko, V. V. et al.
Advanced Materials - Techniques, Physics, Mechanics and Applications. ed. / Muaffaq A. Jani; Ivan A. Parinov; Shun-Hsyung Chang. Springer Science and Business Media, LLC, 2017. p. 155-165 (Springer Proceedings in Physics; Vol. 193).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

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T1 - Mössbauer study of the effect of mechanical activation on the magnetic properties of PbFe0.5Nb0.5O3

AU - Kubrin, S. P.

AU - Raevski, I. P.

AU - Stashenko, V. V.

AU - Gusev, A. A.

AU - Isupov, V. P.

AU - Chen, H. D.

AU - Chou, C. C.

AU - Sarychev, D. A.

AU - Titov, V. V.

AU - Raevskaya, S. I.

PY - 2017/1/1

Y1 - 2017/1/1

N2 - Mössbauer studies of PbFe0.5Nb0.5O3 samples prepared by mechanical activation of PbO, Fe2O3 and Nb2O5 mixture and subsequent sintering at various temperatures TS were performed. The room temperature Mössbauer spectra consist of two doublets (D1 and D2) for the samples with TS < 800 °C and one doublet (D1) for the samples with TS > 800 °C. The parameters of the doublet D1 correspond to Fe3+ in the octahedron environment. Doublet D2 has a lower isomer shift corresponding to Fe3+ with the coordination number 5 that indicates the presence of oxygen vacancies. Dependence of the temperature TN of magnetic phase transition on TS has a maximum at TS ≈ 700 °C. The effect of Fe3+/Nb5+ ordering degree and oxygen deficiency on TN is discussed.

AB - Mössbauer studies of PbFe0.5Nb0.5O3 samples prepared by mechanical activation of PbO, Fe2O3 and Nb2O5 mixture and subsequent sintering at various temperatures TS were performed. The room temperature Mössbauer spectra consist of two doublets (D1 and D2) for the samples with TS < 800 °C and one doublet (D1) for the samples with TS > 800 °C. The parameters of the doublet D1 correspond to Fe3+ in the octahedron environment. Doublet D2 has a lower isomer shift corresponding to Fe3+ with the coordination number 5 that indicates the presence of oxygen vacancies. Dependence of the temperature TN of magnetic phase transition on TS has a maximum at TS ≈ 700 °C. The effect of Fe3+/Nb5+ ordering degree and oxygen deficiency on TN is discussed.

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DO - 10.1007/978-3-319-56062-5_14

M3 - Conference contribution

AN - SCOPUS:85028320753

SN - 9783319560618

T3 - Springer Proceedings in Physics

SP - 155

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BT - Advanced Materials - Techniques, Physics, Mechanics and Applications

A2 - Jani, Muaffaq A.

A2 - Parinov, Ivan A.

A2 - Chang, Shun-Hsyung

PB - Springer Science and Business Media, LLC

T2 - International Conference on Physics, Mechanics of New Materials and Their Applications, PHENMA 2016

Y2 - 19 July 2016 through 22 July 2016

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Kubrin SP, Raevski IP, Stashenko VV, Gusev AA, Isupov VP, Chen HD et al. Mössbauer study of the effect of mechanical activation on the magnetic properties of PbFe_0.5Nb_0.5O₃. In Jani MA, Parinov IA, Chang SH, editors, Advanced Materials - Techniques, Physics, Mechanics and Applications. Springer Science and Business Media, LLC. 2017. p. 155-165. (Springer Proceedings in Physics). doi: 10.1007/978-3-319-56062-5_14