Linestrengths in the 3-0 vibration-rotational band of gaseous 1H35Cl and the electric dipole moment function

J. F. Ogilvie; Yuan-Pern Lee

doi:10.1016/0009-2614(89)87417-2

Linestrengths in the 3-0 vibration-rotational band of gaseous ¹H³⁵Cl and the electric dipole moment function

J. F. Ogilvie^*, Yuan-Pern Lee

^*Corresponding author for this work

Department of Applied Chemistry

Research output: Contribution to journal › Article › peer-review

19 Scopus citations

Abstract

Linestrengths in the 3-0 band of ¹H³⁵Cl and ¹H³⁷Cl have been remeasured. The mean value obtained for the pure vibrational transition matrix element < 0|M(R)| 3 > of ¹HCl is + (1.875 ± 0.024) × 10^-33 C m. Based on this value, a value of < 0|M(R)| 2 > from Boulet et al. which is confirmed, and other published data, a new determination of the electric dipole moment function of HCl has been made in both the M(x) and M(z) representations.

Original language	English
Pages (from-to)	239-243
Number of pages	5
Journal	Chemical Physics Letters
Volume	159
Issue number	2-3
DOIs	https://doi.org/10.1016/0009-2614(89)87417-2
State	Published - 7 Jul 1989

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title = "Linestrengths in the 3-0 vibration-rotational band of gaseous 1H35Cl and the electric dipole moment function",

abstract = "Linestrengths in the 3-0 band of 1H35Cl and 1H37Cl have been remeasured. The mean value obtained for the pure vibrational transition matrix element < 0|M(R)| 3 > of 1HCl is + (1.875 ± 0.024) × 10-33 C m. Based on this value, a value of < 0|M(R)| 2 > from Boulet et al. which is confirmed, and other published data, a new determination of the electric dipole moment function of HCl has been made in both the M(x) and M(z) representations.",

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AU - Ogilvie, J. F.

AU - Lee, Yuan-Pern

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Y1 - 1989/7/7

N2 - Linestrengths in the 3-0 band of 1H35Cl and 1H37Cl have been remeasured. The mean value obtained for the pure vibrational transition matrix element < 0|M(R)| 3 > of 1HCl is + (1.875 ± 0.024) × 10-33 C m. Based on this value, a value of < 0|M(R)| 2 > from Boulet et al. which is confirmed, and other published data, a new determination of the electric dipole moment function of HCl has been made in both the M(x) and M(z) representations.

AB - Linestrengths in the 3-0 band of 1H35Cl and 1H37Cl have been remeasured. The mean value obtained for the pure vibrational transition matrix element < 0|M(R)| 3 > of 1HCl is + (1.875 ± 0.024) × 10-33 C m. Based on this value, a value of < 0|M(R)| 2 > from Boulet et al. which is confirmed, and other published data, a new determination of the electric dipole moment function of HCl has been made in both the M(x) and M(z) representations.

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ER -

Linestrengths in the 3-0 vibration-rotational band of gaseous ¹H³⁵Cl and the electric dipole moment function

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