Laser-induced reactions of NO2 in the visible region - III. Adamantane nitration in the liquid phase

M. E. Umstead; Ming-Chang Lin

doi:10.1007/BF00695594

Laser-induced reactions of NO₂ in the visible region - III. Adamantane nitration in the liquid phase

M. E. Umstead^*, Ming-Chang Lin

^*Corresponding author for this work

Department of Applied Chemistry

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

1-Nitroadamantane was produced by irradiating a solution of adamantane and NO₂ in CCl₄ with the visible lines (457.9-514.5 nm) of an argon-ion laser. At these wavelengths NO₂ does not photodissociate to form O atoms, and thus the nitration reaction must be initiated by another species, probably vibronically excited NO₂ (NO₂ ^*†). The intensity of the laser enables the reaction to be carried out in a reasonable length of time, despite the strong quenching of NO₂ ^*† by CCl₄.

Original language	English
Pages (from-to)	61-63
Number of pages	3
Journal	Applied Physics B Photophysics and Laser Chemistry
Volume	39
Issue number	1
DOIs	https://doi.org/10.1007/BF00695594
State	Published - 1 Jan 1986

Keywords

82.30
82.50

Access to Document

10.1007/BF00695594

Cite this

@article{805379cf6527423fbb7e7d1dfb045d9c,

title = "Laser-induced reactions of NO2 in the visible region - III. Adamantane nitration in the liquid phase",

abstract = "1-Nitroadamantane was produced by irradiating a solution of adamantane and NO2 in CCl4 with the visible lines (457.9-514.5 nm) of an argon-ion laser. At these wavelengths NO2 does not photodissociate to form O atoms, and thus the nitration reaction must be initiated by another species, probably vibronically excited NO2 (NO2 *†). The intensity of the laser enables the reaction to be carried out in a reasonable length of time, despite the strong quenching of NO2 *† by CCl4.",

keywords = "82.30, 82.50",

author = "Umstead, {M. E.} and Ming-Chang Lin",

year = "1986",

month = jan,

day = "1",

doi = "10.1007/BF00695594",

language = "English",

volume = "39",

pages = "61--63",

journal = "Applied Physics B Photophysics and Laser Chemistry",

issn = "0721-7269",

publisher = "Springer Verlag",

number = "1",

}

TY - JOUR

T1 - Laser-induced reactions of NO2 in the visible region - III. Adamantane nitration in the liquid phase

AU - Umstead, M. E.

AU - Lin, Ming-Chang

PY - 1986/1/1

Y1 - 1986/1/1

N2 - 1-Nitroadamantane was produced by irradiating a solution of adamantane and NO2 in CCl4 with the visible lines (457.9-514.5 nm) of an argon-ion laser. At these wavelengths NO2 does not photodissociate to form O atoms, and thus the nitration reaction must be initiated by another species, probably vibronically excited NO2 (NO2 *†). The intensity of the laser enables the reaction to be carried out in a reasonable length of time, despite the strong quenching of NO2 *† by CCl4.

AB - 1-Nitroadamantane was produced by irradiating a solution of adamantane and NO2 in CCl4 with the visible lines (457.9-514.5 nm) of an argon-ion laser. At these wavelengths NO2 does not photodissociate to form O atoms, and thus the nitration reaction must be initiated by another species, probably vibronically excited NO2 (NO2 *†). The intensity of the laser enables the reaction to be carried out in a reasonable length of time, despite the strong quenching of NO2 *† by CCl4.

KW - 82.30

KW - 82.50

UR - http://www.scopus.com/inward/record.url?scp=0022525728&partnerID=8YFLogxK

U2 - 10.1007/BF00695594

DO - 10.1007/BF00695594

M3 - Article

AN - SCOPUS:0022525728

SN - 0721-7269

VL - 39

SP - 61

EP - 63

JO - Applied Physics B Photophysics and Laser Chemistry

JF - Applied Physics B Photophysics and Laser Chemistry

IS - 1

ER -

Laser-induced reactions of NO₂ in the visible region - III. Adamantane nitration in the liquid phase

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this