TY - JOUR
T1 - Laser-induced fluorescence of NO isolated in solid p-H2
AU - Huang, Shang Chen
AU - Lee, Yuan-Pern
PY - 2016/11/16
Y1 - 2016/11/16
N2 - The p-H2 matrix has emerged as a novel host for matrix isolation partly because of its diminished cage effect. So far, most spectral investigations were performed with infrared absorption. We investigated the fluorescence of NO isolated in solid p-H2 upon irradiation at 193 nm and observed emission from the A 2Σ + (v = 1), A 2Σ + (v = 0), B 2Π, and a 4Π states, which is distinct from preceding reports of NO in noble-gas matrices. The unique properties of p-H2 for electronic transitions, such as a small matrix shift on T00 and distinct phonon interactions, are discussed.
AB - The p-H2 matrix has emerged as a novel host for matrix isolation partly because of its diminished cage effect. So far, most spectral investigations were performed with infrared absorption. We investigated the fluorescence of NO isolated in solid p-H2 upon irradiation at 193 nm and observed emission from the A 2Σ + (v = 1), A 2Σ + (v = 0), B 2Π, and a 4Π states, which is distinct from preceding reports of NO in noble-gas matrices. The unique properties of p-H2 for electronic transitions, such as a small matrix shift on T00 and distinct phonon interactions, are discussed.
UR - http://www.scopus.com/inward/record.url?scp=84994059363&partnerID=8YFLogxK
U2 - 10.1016/j.cplett.2016.10.045
DO - 10.1016/j.cplett.2016.10.045
M3 - Article
AN - SCOPUS:84994059363
SN - 0009-2614
VL - 665
SP - 53
EP - 58
JO - Chemical Physics Letters
JF - Chemical Physics Letters
ER -