Kinetics of the C6H5 + CCl4 reaction in the gas phase. Comparison with liquid-phase data

T. Yu; Ming-Chang Lin

doi:10.1021/j100090a602

Kinetics of the C₆H₅ + CCl₄ reaction in the gas phase. Comparison with liquid-phase data

T. Yu^*, Ming-Chang Lin

^*Corresponding author for this work

Department of Applied Chemistry

Research output: Contribution to journal › Article › peer-review

43 Scopus citations

Abstract

The absolute rate constant for the C₆H₅ + CCl₄ reaction, an important reference process employed in numerous kinetic studies in solution, has been measured for the first time with the cavity-ring-down method in the gas phase at temperatures between 298 and 523 K. A weighted least-squares analysis of our gas-phase kinetic data gives k_CCl(4) = 10_9.10±0.08 exp[- 1397 ± 83) /T] M^-1 s^-1. Our values obtained at 298, 318, and 333 K compare reasonably well with those measured in solution by means of relative product formation and transient kinetic determination.

Original language	English
Pages (from-to)	9697-9699
Number of pages	3
Journal	Journal of physical chemistry
Volume	98
Issue number	39
DOIs	https://doi.org/10.1021/j100090a602
State	Published - 1 Jan 1994

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title = "Kinetics of the C6H5 + CCl4 reaction in the gas phase. Comparison with liquid-phase data",

abstract = "The absolute rate constant for the C6H5 + CCl4 reaction, an important reference process employed in numerous kinetic studies in solution, has been measured for the first time with the cavity-ring-down method in the gas phase at temperatures between 298 and 523 K. A weighted least-squares analysis of our gas-phase kinetic data gives kCCl(4) = 109.10±0.08 exp[- 1397 ± 83) /T] M-1 s-1. Our values obtained at 298, 318, and 333 K compare reasonably well with those measured in solution by means of relative product formation and transient kinetic determination.",

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T1 - Kinetics of the C6H5 + CCl4 reaction in the gas phase. Comparison with liquid-phase data

AU - Yu, T.

AU - Lin, Ming-Chang

PY - 1994/1/1

Y1 - 1994/1/1

N2 - The absolute rate constant for the C6H5 + CCl4 reaction, an important reference process employed in numerous kinetic studies in solution, has been measured for the first time with the cavity-ring-down method in the gas phase at temperatures between 298 and 523 K. A weighted least-squares analysis of our gas-phase kinetic data gives kCCl(4) = 109.10±0.08 exp[- 1397 ± 83) /T] M-1 s-1. Our values obtained at 298, 318, and 333 K compare reasonably well with those measured in solution by means of relative product formation and transient kinetic determination.

AB - The absolute rate constant for the C6H5 + CCl4 reaction, an important reference process employed in numerous kinetic studies in solution, has been measured for the first time with the cavity-ring-down method in the gas phase at temperatures between 298 and 523 K. A weighted least-squares analysis of our gas-phase kinetic data gives kCCl(4) = 109.10±0.08 exp[- 1397 ± 83) /T] M-1 s-1. Our values obtained at 298, 318, and 333 K compare reasonably well with those measured in solution by means of relative product formation and transient kinetic determination.

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JO - Journal of physical chemistry

JF - Journal of physical chemistry

IS - 39

ER -

Kinetics of the C₆H₅ + CCl₄ reaction in the gas phase. Comparison with liquid-phase data

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