Kinetics of free radical polymerizations in reactive polymer processing

Y. J. Huang; Ly James Lee

doi:10.1002/aic.690311002

Kinetics of free radical polymerizations in reactive polymer processing

Y. J. Huang, Ly James Lee^*

^*Corresponding author for this work

Institute of Biopharmaceutical Sciences

Research output: Contribution to journal › Article › peer-review

49 Scopus citations

Abstract

A kinetic model has been developed for radical chain growth type of reactive polymer processing operations. This model incorporates considerations of the molecular diffusion that is described by a free volume theory and the basic reaction mechanism of the free‐radical chain polymerization. Experimental results from the bulk styrene polymerization and a reaction of sheet molding compound (SMC) showed good agreement with the model.

Original language	English
Pages (from-to)	1585-1593
Number of pages	9
Journal	AIChE Journal
Volume	31
Issue number	10
DOIs	https://doi.org/10.1002/aic.690311002
State	Published - Oct 1985

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title = "Kinetics of free radical polymerizations in reactive polymer processing",

abstract = "A kinetic model has been developed for radical chain growth type of reactive polymer processing operations. This model incorporates considerations of the molecular diffusion that is described by a free volume theory and the basic reaction mechanism of the free‐radical chain polymerization. Experimental results from the bulk styrene polymerization and a reaction of sheet molding compound (SMC) showed good agreement with the model.",

author = "Huang, {Y. J.} and Lee, {Ly James}",

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AB - A kinetic model has been developed for radical chain growth type of reactive polymer processing operations. This model incorporates considerations of the molecular diffusion that is described by a free volume theory and the basic reaction mechanism of the free‐radical chain polymerization. Experimental results from the bulk styrene polymerization and a reaction of sheet molding compound (SMC) showed good agreement with the model.

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Kinetics of free radical polymerizations in reactive polymer processing

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