Isomers of Ge2N2: Production and infrared absorption of GeNNGe in solid N2

Mohammed Bahou; K. Sankaran; Yu Jong Wu; Yuan-Pern Lee; David Rayner; Benoit Simard

doi:10.1063/1.1569907

Isomers of Ge₂N₂: Production and infrared absorption of GeNNGe in solid N₂

Mohammed Bahou, K. Sankaran, Yu Jong Wu, Yuan-Pern Lee^*, David Rayner, Benoit Simard

^*Corresponding author for this work

Department of Applied Chemistry

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

Laser-ablated Ge reacts with N₂ to form a new species that absorbs near 887.9 cm^-1. Based on observed and calculated vibrational wave numbers and Ge- and N-isotopic shifts, the carrier of observed feature to be linear GeNNGe. Experimental observations that the N-N bond remains intact and that the concentration of linear GeNNGe became enhanced at an increased temperature of deposition and after annealing are consistent with this mechanism.

Original language	English
Pages (from-to)	9710-9718
Number of pages	9
Journal	Journal of Chemical Physics
Volume	118
Issue number	21
DOIs	https://doi.org/10.1063/1.1569907
State	Published - 1 Jun 2003

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abstract = "Laser-ablated Ge reacts with N2 to form a new species that absorbs near 887.9 cm-1. Based on observed and calculated vibrational wave numbers and Ge- and N-isotopic shifts, the carrier of observed feature to be linear GeNNGe. Experimental observations that the N-N bond remains intact and that the concentration of linear GeNNGe became enhanced at an increased temperature of deposition and after annealing are consistent with this mechanism.",

author = "Mohammed Bahou and K. Sankaran and Wu, {Yu Jong} and Yuan-Pern Lee and David Rayner and Benoit Simard",

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AU - Bahou, Mohammed

AU - Sankaran, K.

AU - Wu, Yu Jong

AU - Lee, Yuan-Pern

AU - Rayner, David

AU - Simard, Benoit

PY - 2003/6/1

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N2 - Laser-ablated Ge reacts with N2 to form a new species that absorbs near 887.9 cm-1. Based on observed and calculated vibrational wave numbers and Ge- and N-isotopic shifts, the carrier of observed feature to be linear GeNNGe. Experimental observations that the N-N bond remains intact and that the concentration of linear GeNNGe became enhanced at an increased temperature of deposition and after annealing are consistent with this mechanism.

AB - Laser-ablated Ge reacts with N2 to form a new species that absorbs near 887.9 cm-1. Based on observed and calculated vibrational wave numbers and Ge- and N-isotopic shifts, the carrier of observed feature to be linear GeNNGe. Experimental observations that the N-N bond remains intact and that the concentration of linear GeNNGe became enhanced at an increased temperature of deposition and after annealing are consistent with this mechanism.

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Isomers of Ge₂N₂: Production and infrared absorption of GeNNGe in solid N₂

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