Hydroalkylation of Alkenes Using Alkyl Iodides and Hantzsch Ester under Palladium/Light System

Shuhei Sumino, Ilhyong Ryu*

*Corresponding author for this work

    Research output: Contribution to journalArticlepeer-review

    25 Scopus citations

    Abstract

    The hydroalkylation of alkenes using alkyl iodides with Hantzsch ester as a hydrogen source occurred smoothly under a Pd/light system, in a novel, tin-free Giese reaction. A chemoselective reaction at C(sp3)-I in the presence of a C(sp2)-X (X = Br or I) bond was attained, which allowed for the stepwise functionalization of two types of C-X bonds in a one-pot procedure.

    Original languageEnglish
    Pages (from-to)52-55
    Number of pages4
    JournalOrganic Letters
    Volume18
    Issue number1
    DOIs
    StatePublished - 4 Jan 2016

    Fingerprint

    Dive into the research topics of 'Hydroalkylation of Alkenes Using Alkyl Iodides and Hantzsch Ester under Palladium/Light System'. Together they form a unique fingerprint.

    Cite this