Holographic characteristics of organo-metallic compound doped PQ: PMMA photopolymers

Yi Nan Hsiao; Wha Tzong Whang; Shiuan-Huei Lin; Ken-Yuh Hsu

doi:10.1117/12.560426

Holographic characteristics of organo-metallic compound doped PQ: PMMA photopolymers

Yi Nan Hsiao^*, Wha Tzong Whang, Shiuan-Huei Lin, Ken-Yuh Hsu

^*Corresponding author for this work

Research output: Contribution to journal › Conference article › peer-review

6 Scopus citations

Abstract

Photopolymers have been applied widely in optical devices for communications, displays, bio-sensing, and data storage. The advantages of this material are easy to synthesize, high refractive index change, high sensitivity and good optical quality. Recently, we have investigated on the syntheses and analysis of 9,10-PhenanthreneQuinone doped Poly(Methyl MethAcrylate) (PQ:PMMA) photopolymer. This material can be fabricated with large dimensions and with thickness in the range of several-centimeters. Experiments show that the material shrinkage is negligible after optical exposure such that our doped photopolymer is attractive for volume holographic applications. However, comparing with other photopolymers, our PQrPMMA material has a drawback of lower sensitivity (∼10 mW/cm²). In this presentation, we demonstrate that by adding organo-metallic compound (Zinc MethylAcrylate, ZnMA) into the PQ:PMMA photopolymer. we succeeded in reducing response time and increasing holographic diffraction efficiency of the material. We report the fabrication and experimental investigation of dye-doped photopolymer, and discuss their application for data storage.

Original language	English
Article number	05
Pages (from-to)	34-44
Number of pages	11
Journal	Proceedings of SPIE - The International Society for Optical Engineering
Volume	5560
DOIs	https://doi.org/10.1117/12.560426
State	Published - 2004
Event	Photorefractive Fiber and Crystal Devices: Materials, Optical Properties, and Applications X - Denver, CO, United States Duration: 2 Aug 2004 → 3 Aug 2004

Keywords

Organo-metallic molecule
PMMA
Photopolymer
Volume hologram

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title = "Holographic characteristics of organo-metallic compound doped PQ: PMMA photopolymers",

abstract = "Photopolymers have been applied widely in optical devices for communications, displays, bio-sensing, and data storage. The advantages of this material are easy to synthesize, high refractive index change, high sensitivity and good optical quality. Recently, we have investigated on the syntheses and analysis of 9,10-PhenanthreneQuinone doped Poly(Methyl MethAcrylate) (PQ:PMMA) photopolymer. This material can be fabricated with large dimensions and with thickness in the range of several-centimeters. Experiments show that the material shrinkage is negligible after optical exposure such that our doped photopolymer is attractive for volume holographic applications. However, comparing with other photopolymers, our PQrPMMA material has a drawback of lower sensitivity (∼10 mW/cm2). In this presentation, we demonstrate that by adding organo-metallic compound (Zinc MethylAcrylate, ZnMA) into the PQ:PMMA photopolymer. we succeeded in reducing response time and increasing holographic diffraction efficiency of the material. We report the fabrication and experimental investigation of dye-doped photopolymer, and discuss their application for data storage.",

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author = "Hsiao, {Yi Nan} and Whang, {Wha Tzong} and Shiuan-Huei Lin and Ken-Yuh Hsu",

year = "2004",

doi = "10.1117/12.560426",

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journal = "Proceedings of SPIE - The International Society for Optical Engineering",

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T1 - Holographic characteristics of organo-metallic compound doped PQ

T2 - Photorefractive Fiber and Crystal Devices: Materials, Optical Properties, and Applications X

AU - Hsiao, Yi Nan

AU - Whang, Wha Tzong

AU - Lin, Shiuan-Huei

AU - Hsu, Ken-Yuh

PY - 2004

Y1 - 2004

N2 - Photopolymers have been applied widely in optical devices for communications, displays, bio-sensing, and data storage. The advantages of this material are easy to synthesize, high refractive index change, high sensitivity and good optical quality. Recently, we have investigated on the syntheses and analysis of 9,10-PhenanthreneQuinone doped Poly(Methyl MethAcrylate) (PQ:PMMA) photopolymer. This material can be fabricated with large dimensions and with thickness in the range of several-centimeters. Experiments show that the material shrinkage is negligible after optical exposure such that our doped photopolymer is attractive for volume holographic applications. However, comparing with other photopolymers, our PQrPMMA material has a drawback of lower sensitivity (∼10 mW/cm2). In this presentation, we demonstrate that by adding organo-metallic compound (Zinc MethylAcrylate, ZnMA) into the PQ:PMMA photopolymer. we succeeded in reducing response time and increasing holographic diffraction efficiency of the material. We report the fabrication and experimental investigation of dye-doped photopolymer, and discuss their application for data storage.

AB - Photopolymers have been applied widely in optical devices for communications, displays, bio-sensing, and data storage. The advantages of this material are easy to synthesize, high refractive index change, high sensitivity and good optical quality. Recently, we have investigated on the syntheses and analysis of 9,10-PhenanthreneQuinone doped Poly(Methyl MethAcrylate) (PQ:PMMA) photopolymer. This material can be fabricated with large dimensions and with thickness in the range of several-centimeters. Experiments show that the material shrinkage is negligible after optical exposure such that our doped photopolymer is attractive for volume holographic applications. However, comparing with other photopolymers, our PQrPMMA material has a drawback of lower sensitivity (∼10 mW/cm2). In this presentation, we demonstrate that by adding organo-metallic compound (Zinc MethylAcrylate, ZnMA) into the PQ:PMMA photopolymer. we succeeded in reducing response time and increasing holographic diffraction efficiency of the material. We report the fabrication and experimental investigation of dye-doped photopolymer, and discuss their application for data storage.

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KW - Volume hologram

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Y2 - 2 August 2004 through 3 August 2004

ER -

Holographic characteristics of organo-metallic compound doped PQ: PMMA photopolymers

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