Graphene-graphene oxide-graphene hybrid nanopapers with superior mechanical, gas barrier and electrical properties

Hybrid nanopaper-like thin films with a graphene oxide (GO) layer sandwiched by two functionalized graphene (GP-SO₃H) layers were successfully prepared from oxidized graphene and benzene sulfonic modified graphene. The hybrid graphene-graphene oxide-graphene (GP-GO-GP) nanopapers showed combination of high mechanic strength and good electrical conductivity, leading to desirable electromagnetic interference shielding performance, from the GP-SO₃H layers, and superior gas diffusion barrier provided by the GO layer. These GP-GO-GP nanopapers can be readily coated onto plastic and composite substrates by thermal lamination and injection molding for various industrial applications such as fuel cell and natural gas containers.