Fine tuning of the orifice size of an open-cage fullerene by placing selenium in the rim: Insertion/release of molecular hydrogen

Shih-Ching Chuang; Yasujiro Murata; Michihisa Murata; Sadayuki Mori; Shuhei Maeda; Fumiyuki Tanabe; Koichi Komatsu

doi:10.1039/b616478a

Fine tuning of the orifice size of an open-cage fullerene by placing selenium in the rim: Insertion/release of molecular hydrogen

Shih-Ching Chuang, Yasujiro Murata^*, Michihisa Murata, Sadayuki Mori, Shuhei Maeda, Fumiyuki Tanabe, Koichi Komatsu

^*Corresponding author for this work

Department of Applied Chemistry

Research output: Contribution to journal › Article › peer-review

34 Scopus citations

Abstract

A newly synthesized open-cage fullerene containing selenium in the rim of the 13-membered-ring orifice allows milder conditions for hydrogen insertion, and the rate for hydrogen release is ca. three times faster than its sulfur analogue.

Original language	English
Pages (from-to)	1278-1280
Number of pages	3
Journal	Chemical Communications
Issue number	12
DOIs	https://doi.org/10.1039/b616478a
State	Published - 16 Jan 2007

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title = "Fine tuning of the orifice size of an open-cage fullerene by placing selenium in the rim: Insertion/release of molecular hydrogen",

abstract = "A newly synthesized open-cage fullerene containing selenium in the rim of the 13-membered-ring orifice allows milder conditions for hydrogen insertion, and the rate for hydrogen release is ca. three times faster than its sulfur analogue.",

author = "Shih-Ching Chuang and Yasujiro Murata and Michihisa Murata and Sadayuki Mori and Shuhei Maeda and Fumiyuki Tanabe and Koichi Komatsu",

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AU - Chuang, Shih-Ching

AU - Murata, Yasujiro

AU - Murata, Michihisa

AU - Mori, Sadayuki

AU - Maeda, Shuhei

AU - Tanabe, Fumiyuki

AU - Komatsu, Koichi

PY - 2007/1/16

Y1 - 2007/1/16

N2 - A newly synthesized open-cage fullerene containing selenium in the rim of the 13-membered-ring orifice allows milder conditions for hydrogen insertion, and the rate for hydrogen release is ca. three times faster than its sulfur analogue.

AB - A newly synthesized open-cage fullerene containing selenium in the rim of the 13-membered-ring orifice allows milder conditions for hydrogen insertion, and the rate for hydrogen release is ca. three times faster than its sulfur analogue.

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DO - 10.1039/b616478a

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SP - 1278

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JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 12

ER -

Fine tuning of the orifice size of an open-cage fullerene by placing selenium in the rim: Insertion/release of molecular hydrogen

Abstract

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