Experimental and reduced dimensionality quantum rate coefficients for H2(D2)+CN→H(D)CN+H(D)

Q. Sun; D. L. Yang; Niann-Shiah Wang; J. M. Bowman; Ming-Chang Lin

doi:10.1063/1.458663

Experimental and reduced dimensionality quantum rate coefficients for H₂(D₂)+CN→H(D)CN+H(D)

Q. Sun^*, D. L. Yang, Niann-Shiah Wang, J. M. Bowman, Ming-Chang Lin

^*Corresponding author for this work

Department of Applied Chemistry

Research output: Contribution to journal › Article › peer-review

93 Scopus citations

Abstract

New experimental rate coefficients are reported for the H ₂(D₂) + CN→H(D)CN + H(D) reactions over the temperature range 209 to 740 K for H₂ and 250 to 740 K for D ₂. Previous reduced dimensionality reaction probabilities for the reaction with H₂, and new ones for the reaction with D₂ are used to obtain analogous rate coefficients. In addition, reaction probabilities and rate coefficients for vibrationally excited reactants H ₂ (v = 1), D₂ (v = 1), or CN(v = 1) are presented. Comparisons of the calculated rate coefficients are made with the new and previous experiments, especially those of Sims and Smith [Chem. Phys. Lett. 149, 565 (1988)].

Original language	English
Pages (from-to)	4730-4739
Number of pages	10
Journal	The Journal of chemical physics
Volume	93
Issue number	7
DOIs	https://doi.org/10.1063/1.458663
State	Published - 1990

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title = "Experimental and reduced dimensionality quantum rate coefficients for H2(D2)+CN→H(D)CN+H(D)",

abstract = "New experimental rate coefficients are reported for the H 2(D2) + CN→H(D)CN + H(D) reactions over the temperature range 209 to 740 K for H2 and 250 to 740 K for D 2. Previous reduced dimensionality reaction probabilities for the reaction with H2, and new ones for the reaction with D2 are used to obtain analogous rate coefficients. In addition, reaction probabilities and rate coefficients for vibrationally excited reactants H 2 (v = 1), D2 (v = 1), or CN(v = 1) are presented. Comparisons of the calculated rate coefficients are made with the new and previous experiments, especially those of Sims and Smith [Chem. Phys. Lett. 149, 565 (1988)].",

author = "Q. Sun and Yang, {D. L.} and Niann-Shiah Wang and Bowman, {J. M.} and Ming-Chang Lin",

year = "1990",

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journal = "The Journal of chemical physics",

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T1 - Experimental and reduced dimensionality quantum rate coefficients for H2(D2)+CN→H(D)CN+H(D)

AU - Sun, Q.

AU - Yang, D. L.

AU - Wang, Niann-Shiah

AU - Bowman, J. M.

AU - Lin, Ming-Chang

PY - 1990

Y1 - 1990

N2 - New experimental rate coefficients are reported for the H 2(D2) + CN→H(D)CN + H(D) reactions over the temperature range 209 to 740 K for H2 and 250 to 740 K for D 2. Previous reduced dimensionality reaction probabilities for the reaction with H2, and new ones for the reaction with D2 are used to obtain analogous rate coefficients. In addition, reaction probabilities and rate coefficients for vibrationally excited reactants H 2 (v = 1), D2 (v = 1), or CN(v = 1) are presented. Comparisons of the calculated rate coefficients are made with the new and previous experiments, especially those of Sims and Smith [Chem. Phys. Lett. 149, 565 (1988)].

AB - New experimental rate coefficients are reported for the H 2(D2) + CN→H(D)CN + H(D) reactions over the temperature range 209 to 740 K for H2 and 250 to 740 K for D 2. Previous reduced dimensionality reaction probabilities for the reaction with H2, and new ones for the reaction with D2 are used to obtain analogous rate coefficients. In addition, reaction probabilities and rate coefficients for vibrationally excited reactants H 2 (v = 1), D2 (v = 1), or CN(v = 1) are presented. Comparisons of the calculated rate coefficients are made with the new and previous experiments, especially those of Sims and Smith [Chem. Phys. Lett. 149, 565 (1988)].

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JO - The Journal of chemical physics

JF - The Journal of chemical physics

IS - 7

ER -

Experimental and reduced dimensionality quantum rate coefficients for H₂(D₂)+CN→H(D)CN+H(D)

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