Effects of strain on the electronic structure and magnetic properties in SrMn0.5Fe0.5O3

Chun Wei Mi; Yi Ying Chin; Yen Fu Hsiao; Hau Wei Fang; Chih-Wei Luo; Kaung-Hsiung Wu; Tzeng Ming Uen; Jiunn-Yuan Lin; Hong Ji Lin; Jenh-Yih Juang

doi:10.1088/0953-8984/28/34/345501

Effects of strain on the electronic structure and magnetic properties in SrMn_0.5Fe_0.5O₃

Chun Wei Mi, Yi Ying Chin, Yen Fu Hsiao, Hau Wei Fang, Chih-Wei Luo, Kaung-Hsiung Wu, Tzeng Ming Uen, Jiunn-Yuan Lin, Hong Ji Lin, Jenh-Yih Juang

Research output: Contribution to journal › Article › peer-review

Abstract

The electronic structure and magnetic properties of SrMn_0.5Fe_0.5O₃ powder and films grown on (1 0 0)-SrTiO₃ (STO) and (1 0 0)-LaAlO₃ (Lao) substrates by pulsed laser deposition (PLD) were investigated by temperature dependent magnetization and soft x-ray absorption. The results exhibit characteristics of 3d ⁵ Fe³⁺, and 3d³ + 3d ⁴ Mn⁴⁺ at room temperature in all samples. However, the features of 3d ⁵ Fe³⁺ and 3d ³ Mn⁴⁺ increased significantly for SMFO/Lao at 35 K, which also displayed substantial competition between antiferromagnetic and ferromagnetic order well-above the Néel temperature of SrFeO₃ (T _N ∼ 134 K). We attributed this to being caused by charge disproportionation resulting from ligand-hole localization, which is more favorable to take place when the sample is under compressive strain.

Original language	English
Article number	345501
Journal	Journal of Physics Condensed Matter
Volume	28
Issue number	34
DOIs	https://doi.org/10.1088/0953-8984/28/34/345501
State	Published - 29 Jun 2016

Keywords

charge disproportionation
spin-glass
strain effect
strongly correlated system
x-ray absorption spectroscopy

Access to Document

10.1088/0953-8984/28/34/345501

Cite this

@article{62ec5bf31b5543b882b9a3fd8166da66,

title = "Effects of strain on the electronic structure and magnetic properties in SrMn0.5Fe0.5O3",

abstract = "The electronic structure and magnetic properties of SrMn0.5Fe0.5O3 powder and films grown on (1 0 0)-SrTiO3 (STO) and (1 0 0)-LaAlO3 (Lao) substrates by pulsed laser deposition (PLD) were investigated by temperature dependent magnetization and soft x-ray absorption. The results exhibit characteristics of 3d 5 Fe3+, and 3d3 + 3d 4 Mn4+ at room temperature in all samples. However, the features of 3d 5 Fe3+ and 3d 3 Mn4+ increased significantly for SMFO/Lao at 35 K, which also displayed substantial competition between antiferromagnetic and ferromagnetic order well-above the N{\'e}el temperature of SrFeO3 (T N ∼ 134 K). We attributed this to being caused by charge disproportionation resulting from ligand-hole localization, which is more favorable to take place when the sample is under compressive strain.",

keywords = "charge disproportionation, spin-glass, strain effect, strongly correlated system, x-ray absorption spectroscopy",

author = "Mi, {Chun Wei} and Chin, {Yi Ying} and Hsiao, {Yen Fu} and Fang, {Hau Wei} and Chih-Wei Luo and Kaung-Hsiung Wu and Uen, {Tzeng Ming} and Jiunn-Yuan Lin and Lin, {Hong Ji} and Jenh-Yih Juang",

year = "2016",

month = jun,

day = "29",

doi = "10.1088/0953-8984/28/34/345501",

language = "English",

volume = "28",

journal = "Journal of Physics Condensed Matter",

issn = "0953-8984",

publisher = "IOP Publishing Ltd.",

number = "34",

}

TY - JOUR

T1 - Effects of strain on the electronic structure and magnetic properties in SrMn0.5Fe0.5O3

AU - Mi, Chun Wei

AU - Chin, Yi Ying

AU - Hsiao, Yen Fu

AU - Fang, Hau Wei

AU - Luo, Chih-Wei

AU - Wu, Kaung-Hsiung

AU - Uen, Tzeng Ming

AU - Lin, Jiunn-Yuan

AU - Lin, Hong Ji

AU - Juang, Jenh-Yih

PY - 2016/6/29

Y1 - 2016/6/29

N2 - The electronic structure and magnetic properties of SrMn0.5Fe0.5O3 powder and films grown on (1 0 0)-SrTiO3 (STO) and (1 0 0)-LaAlO3 (Lao) substrates by pulsed laser deposition (PLD) were investigated by temperature dependent magnetization and soft x-ray absorption. The results exhibit characteristics of 3d 5 Fe3+, and 3d3 + 3d 4 Mn4+ at room temperature in all samples. However, the features of 3d 5 Fe3+ and 3d 3 Mn4+ increased significantly for SMFO/Lao at 35 K, which also displayed substantial competition between antiferromagnetic and ferromagnetic order well-above the Néel temperature of SrFeO3 (T N ∼ 134 K). We attributed this to being caused by charge disproportionation resulting from ligand-hole localization, which is more favorable to take place when the sample is under compressive strain.

AB - The electronic structure and magnetic properties of SrMn0.5Fe0.5O3 powder and films grown on (1 0 0)-SrTiO3 (STO) and (1 0 0)-LaAlO3 (Lao) substrates by pulsed laser deposition (PLD) were investigated by temperature dependent magnetization and soft x-ray absorption. The results exhibit characteristics of 3d 5 Fe3+, and 3d3 + 3d 4 Mn4+ at room temperature in all samples. However, the features of 3d 5 Fe3+ and 3d 3 Mn4+ increased significantly for SMFO/Lao at 35 K, which also displayed substantial competition between antiferromagnetic and ferromagnetic order well-above the Néel temperature of SrFeO3 (T N ∼ 134 K). We attributed this to being caused by charge disproportionation resulting from ligand-hole localization, which is more favorable to take place when the sample is under compressive strain.

KW - charge disproportionation

KW - spin-glass

KW - strain effect

KW - strongly correlated system

KW - x-ray absorption spectroscopy

UR - http://www.scopus.com/inward/record.url?scp=84978881322&partnerID=8YFLogxK

U2 - 10.1088/0953-8984/28/34/345501

DO - 10.1088/0953-8984/28/34/345501

M3 - Article

AN - SCOPUS:84978881322

SN - 0953-8984

VL - 28

JO - Journal of Physics Condensed Matter

JF - Journal of Physics Condensed Matter

IS - 34

M1 - 345501

ER -

Effects of strain on the electronic structure and magnetic properties in SrMn_0.5Fe_0.5O₃

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this