Donor-Promoted 1,2-Hydrogen Migration from Silicon to a Saturated Ruthenium Center and Access to Silaoxiranyl and Silaiminyl Complexes

Keyphrases

• Hydrogen Migration 100%
• Ruthenium 100%
• Benzophenone 66%
• Electron-deficient 33%
• Electron-rich 33%
• Silane 33%
• Transition State 33%
• Formation Mechanism 33%
• Electron Transfer 33%
• DFT Calculations 33%
• Deprotonated 33%
• Si-H Bonds 33%
• Ketones 33%
• Enones 33%
• Silylene Complexes 33%
• Imidazol-2-ylidene 33%
• Silylenes 33%
• Tosyl Azide 33%
• Silicon Atom 33%
• Innocent 33%
• Silicon-containing 33%
• Diradicaloids 33%
• Single Electron Transfer 33%

Chemistry

• Hydrogen 100%
• Donor 100%
• Silicon 100%
• Ruthenium 100%
• Benzophenone 66%
• Electron Transport 66%
• Ketones 33%
• Transition State 33%
• Azide 33%
• Enone 33%
• Silicon Atom 33%
• formation 33%
• Density Functional Theory 33%