Direct observation of denitrogenation process of 2,3-diazabicyclo[2.2.1] hept-2-ene (DBH) derivatives, using a visible 5-fs pulse laser

Manabu Abe*, Izumi Iwakura, Atsushi Yabushita, Shingo Yagi, Jun Liu, Kotaro Okamura, Takayoshi Kobayashi

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

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Abstract

The mechanism of denitrogenation for 2,3-diazabicyclo[2.2.1]hept-2-ene (DBH) derivatives was investigated using a visible 5-fs pulse laser. The time-dependent wavenumber changes observed in this study revealed that the concerted denitrogenation occurs in the parent DBH. However, a stepwise denitrogenation mechanism was found for the 7,7-diethoxy-substituted DBH derivative.

Original languageEnglish
Pages (from-to)79-83
Number of pages5
JournalChemical Physics Letters
Volume527
DOIs
StatePublished - 27 Feb 2012

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