Copper(II)-Mediated Stereoselective Reduction of Acetylenic Sulfones by Hydrosilanes

Ilhyong Ryu*, Nobuo Kusumoto, Akiya Ogawa, Nobuaki Kambe, Noboru Sonoda

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

28 Scopus citations

Abstract

The stereoselective reduction of acetylenic sulfones to cis vinylic sulfones was effected by using a novel reduction system consisting of copper(II) salts (Cu(Bf4)2, Cu(OTf)2, CuF2, etc.) and a hydrosilane. The best result was obtained by the use of Cu(BF4)2. A divalent copper hydride is proposed to be responsible for this reduction.

Original languageEnglish
Pages (from-to)2279-2281
Number of pages3
JournalOrganometallics
Volume8
Issue number9
DOIs
StatePublished - 1 Jan 1989

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