Carbonylation of Alkyl Radicals Derived from Organosilicates through Visible-Light Photoredox Catalysis

Alex Cartier; Etienne Levernier; Vincent Corcé; Takahide Fukuyama; Anne Lise Dhimane; Cyril Ollivier; Ilhyong Ryu; Louis Fensterbank

doi:10.1002/anie.201811858

Carbonylation of Alkyl Radicals Derived from Organosilicates through Visible-Light Photoredox Catalysis

Alex Cartier, Etienne Levernier, Vincent Corcé, Takahide Fukuyama^*, Anne Lise Dhimane, Cyril Ollivier, Ilhyong Ryu, Louis Fensterbank

^*Corresponding author for this work

Department of Applied Chemistry

Research output: Contribution to journal › Article › peer-review

72 Scopus citations

Abstract

Primary, secondary, and tertiary alkyl radicals formed by the photocatalyzed oxidation of organosilicates underwent efficient carbonylation with carbon monoxide (CO) to give a variety of unsymmetrical ketones. This study introduces the possibility of radical carbonylation under a photooxidative regime.

Original language	English
Pages (from-to)	1789-1793
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	58
Issue number	6
DOIs	https://doi.org/10.1002/anie.201811858
State	Published - 4 Feb 2019

Keywords

carbonylation
photocatalysis
radicals
silicates
three-component reactions

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10.1002/anie.201811858

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title = "Carbonylation of Alkyl Radicals Derived from Organosilicates through Visible-Light Photoredox Catalysis",

abstract = "Primary, secondary, and tertiary alkyl radicals formed by the photocatalyzed oxidation of organosilicates underwent efficient carbonylation with carbon monoxide (CO) to give a variety of unsymmetrical ketones. This study introduces the possibility of radical carbonylation under a photooxidative regime.",

keywords = "carbonylation, photocatalysis, radicals, silicates, three-component reactions",

author = "Alex Cartier and Etienne Levernier and Vincent Corc{\'e} and Takahide Fukuyama and Dhimane, {Anne Lise} and Cyril Ollivier and Ilhyong Ryu and Louis Fensterbank",

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AU - Cartier, Alex

AU - Levernier, Etienne

AU - Corcé, Vincent

AU - Fukuyama, Takahide

AU - Dhimane, Anne Lise

AU - Ollivier, Cyril

AU - Ryu, Ilhyong

AU - Fensterbank, Louis

PY - 2019/2/4

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N2 - Primary, secondary, and tertiary alkyl radicals formed by the photocatalyzed oxidation of organosilicates underwent efficient carbonylation with carbon monoxide (CO) to give a variety of unsymmetrical ketones. This study introduces the possibility of radical carbonylation under a photooxidative regime.

AB - Primary, secondary, and tertiary alkyl radicals formed by the photocatalyzed oxidation of organosilicates underwent efficient carbonylation with carbon monoxide (CO) to give a variety of unsymmetrical ketones. This study introduces the possibility of radical carbonylation under a photooxidative regime.

KW - carbonylation

KW - photocatalysis

KW - radicals

KW - silicates

KW - three-component reactions

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JF - Angewandte Chemie - International Edition

IS - 6

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Carbonylation of Alkyl Radicals Derived from Organosilicates through Visible-Light Photoredox Catalysis

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Keywords

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