Carbonylation of Alkyl Radicals Derived from Organosilicates through Visible-Light Photoredox Catalysis

Alex Cartier, Etienne Levernier, Vincent Corcé, Takahide Fukuyama*, Anne Lise Dhimane, Cyril Ollivier, Ilhyong Ryu, Louis Fensterbank

*Corresponding author for this work

    Research output: Contribution to journalArticlepeer-review

    32 Scopus citations

    Abstract

    Primary, secondary, and tertiary alkyl radicals formed by the photocatalyzed oxidation of organosilicates underwent efficient carbonylation with carbon monoxide (CO) to give a variety of unsymmetrical ketones. This study introduces the possibility of radical carbonylation under a photooxidative regime.

    Original languageEnglish
    Pages (from-to)1789-1793
    Number of pages5
    JournalAngewandte Chemie - International Edition
    Volume58
    Issue number6
    DOIs
    StatePublished - 4 Feb 2019

    Keywords

    • carbonylation
    • photocatalysis
    • radicals
    • silicates
    • three-component reactions

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