Allylative ring opening of siloxycyclopropanes by silver fluoride and allylic chlorides affording δ, ε-unsaturated ketones

Ilhyong Ryu*, Haruhisa Suzuki, Akiya Ogawa, Nobuaki Kambe, Noboru Sonoda

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

17 Scopus citations

Abstract

Unconventional type of allylation reaction at the β-position of ketone carbonyl has been developed based on the β-metallo ketone strategy: treatment of siloxycyclopropanes 1 with allylic chlorides 2 in the presence of silver fluoride results in the effective formation of δ, ε-unsaturated ketones 4.

Original languageEnglish
Pages (from-to)6137-6140
Number of pages4
JournalTetrahedron Letters
Volume29
Issue number47
DOIs
StatePublished - 1 Jan 1988

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