A transition-metal-free cross-coupling reaction of allylic bromides with aryl- and vinylboronic acids

Mitsuhiro Ueda*, Kota Nishimura, Ryo Kashima, Ilhyong Ryu

*Corresponding author for this work

    Research output: Contribution to journalReview articlepeer-review

    21 Scopus citations

    Abstract

    A cross-coupling reaction between aryl- and vinylboronic acids and various allylic bromides proceeded without the use of a transition-metal catalyst to give the corresponding allylated products in moderate to good yields. The use of an inorganic base (KF or CsO and a small amount of water is crucial in obtaining good performance in the present transition-metal-free reaction.

    Original languageEnglish
    Pages (from-to)1085-1089
    Number of pages5
    JournalSynlett
    Volume23
    Issue number7
    DOIs
    StatePublished - 29 Mar 2012

    Keywords

    • aryl- and vinylboronic acids
    • C-C bond formation
    • transition-metal-free

    Fingerprint

    Dive into the research topics of 'A transition-metal-free cross-coupling reaction of allylic bromides with aryl- and vinylboronic acids'. Together they form a unique fingerprint.

    Cite this