A Palladium/Light System Combined with Hanztsch Ester: Radical Vinylation of Alkyl Iodides with Vinyl Bromides

Shuhei Sumino, Ilhyong Ryu*

*Corresponding author for this work

    Research output: Contribution to journalArticlepeer-review

    9 Scopus citations

    Abstract

    Radical vinylation of alkyl iodides with vinyl bromides proceeds smoothly with a combined Pd/light/Hanztsch ester system. In this reaction system, the Hanztsch ester acts as an effective reducing reagent of PdII to Pd0 that generates key alkyl radicals via single electron transfer (SET) with alkyl iodides upon photo-excitation.

    Original languageEnglish
    Pages (from-to)410-413
    Number of pages4
    JournalAsian Journal of Organic Chemistry
    Volume6
    Issue number4
    DOIs
    StatePublished - Apr 2017

    Keywords

    • Hanztsch ester
    • palladium
    • photocatalysis
    • radical reactions
    • redox chemistry

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