A New Protocol for Catalytic Reduction of Alkyl Chlorides Using an Iridium/Bis(benzimidazol-2′-yl)pyridine Catalyst and Triethylsilane

Takahide Fukuyama; Yuki Hamada; Ilhyong Ryu

doi:10.1055/a-1527-4526

A New Protocol for Catalytic Reduction of Alkyl Chlorides Using an Iridium/Bis(benzimidazol-2′-yl)pyridine Catalyst and Triethylsilane

Takahide Fukuyama^*, Yuki Hamada, Ilhyong Ryu

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

The reduction of alkyl chlorides using triethylsilane is investigated. Primary, secondary, tertiary, and benzylic C-Cl bonds are effectively converted into C-H bonds using an [IrCl(cod)] ₂/2,6-bis(benzimidazol-2′-yl)pyridine catalyst system. This catalyst system is quite simple since the tridentate N-ligand can be easily prepared in one step from commercially available reagents.

Original language	English
Article number	ss-2021-f0258-st
Pages (from-to)	3404-3408
Number of pages	5
Journal	Synthesis (Germany)
Volume	53
Issue number	18
DOIs	https://doi.org/10.1055/a-1527-4526
State	Published - 16 Sep 2021

Keywords

alkyl chlorides
iridium catalyst
nitrogen ligand
reduction
triethylsilane

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10.1055/a-1527-4526

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abstract = "The reduction of alkyl chlorides using triethylsilane is investigated. Primary, secondary, tertiary, and benzylic C-Cl bonds are effectively converted into C-H bonds using an [IrCl(cod)] 2/2,6-bis(benzimidazol-2′-yl)pyridine catalyst system. This catalyst system is quite simple since the tridentate N-ligand can be easily prepared in one step from commercially available reagents.",

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AU - Ryu, Ilhyong

PY - 2021/9/16

Y1 - 2021/9/16

N2 - The reduction of alkyl chlorides using triethylsilane is investigated. Primary, secondary, tertiary, and benzylic C-Cl bonds are effectively converted into C-H bonds using an [IrCl(cod)] 2/2,6-bis(benzimidazol-2′-yl)pyridine catalyst system. This catalyst system is quite simple since the tridentate N-ligand can be easily prepared in one step from commercially available reagents.

AB - The reduction of alkyl chlorides using triethylsilane is investigated. Primary, secondary, tertiary, and benzylic C-Cl bonds are effectively converted into C-H bonds using an [IrCl(cod)] 2/2,6-bis(benzimidazol-2′-yl)pyridine catalyst system. This catalyst system is quite simple since the tridentate N-ligand can be easily prepared in one step from commercially available reagents.

KW - alkyl chlorides

KW - iridium catalyst

KW - nitrogen ligand

KW - reduction

KW - triethylsilane

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A New Protocol for Catalytic Reduction of Alkyl Chlorides Using an Iridium/Bis(benzimidazol-2′-yl)pyridine Catalyst and Triethylsilane

Abstract

Keywords

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