A Hydrogen Pyrophosphate Selective Anion Receptor Based on Thiosemicarbazone

Thiravidamani Senthil Pandian; Venkatesan Srinivasadesikan; Ming-Chang Lin; Jong I.L. Park; Jongmin Kang

doi:10.1002/bkcs.11320

A Hydrogen Pyrophosphate Selective Anion Receptor Based on Thiosemicarbazone

Thiravidamani Senthil Pandian, Venkatesan Srinivasadesikan, Ming-Chang Lin, Jong I.L. Park, Jongmin Kang^*

^*Corresponding author for this work

Department of Applied Chemistry

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

A novel rigid anion receptor 1 containing thiosemicarbazone groups were synthesized. Receptor 1 displayed competitive turn-off fluorescence and colorimetric response for hydrogen pyrophosphate. This recognition process was confirmed by UV–vis, fluorescence titrations. A detailed analysis of the TD-density functional theory calculations was consistent with the observed colorimetric experiments. These experiments revealed that the colorimetric and fluorescent response is triggered by thiourea/ HP₂O₇ ³⁻ hydrogen bonding.

Original language	English
Pages (from-to)	1435-1442
Number of pages	8
Journal	Bulletin of the Korean Chemical Society
Volume	38
Issue number	12
DOIs	https://doi.org/10.1002/bkcs.11320
State	Published - Dec 2017

Keywords

Anion receptor
Hydrogen bonding
Hydrogen pyrophosphate
Thiourea

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10.1002/bkcs.11320

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title = "A Hydrogen Pyrophosphate Selective Anion Receptor Based on Thiosemicarbazone",

abstract = "A novel rigid anion receptor 1 containing thiosemicarbazone groups were synthesized. Receptor 1 displayed competitive turn-off fluorescence and colorimetric response for hydrogen pyrophosphate. This recognition process was confirmed by UV–vis, fluorescence titrations. A detailed analysis of the TD-density functional theory calculations was consistent with the observed colorimetric experiments. These experiments revealed that the colorimetric and fluorescent response is triggered by thiourea/ HP2O7 3− hydrogen bonding.",

keywords = "Anion receptor, Hydrogen bonding, Hydrogen pyrophosphate, Thiourea",

author = "Pandian, {Thiravidamani Senthil} and Venkatesan Srinivasadesikan and Ming-Chang Lin and Park, {Jong I.L.} and Jongmin Kang",

note = "Publisher Copyright: {\textcopyright} 2017 Korean Chemical Society, Seoul & Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.",

year = "2017",

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doi = "10.1002/bkcs.11320",

language = "English",

volume = "38",

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T1 - A Hydrogen Pyrophosphate Selective Anion Receptor Based on Thiosemicarbazone

AU - Pandian, Thiravidamani Senthil

AU - Srinivasadesikan, Venkatesan

AU - Lin, Ming-Chang

AU - Park, Jong I.L.

AU - Kang, Jongmin

PY - 2017/12

Y1 - 2017/12

N2 - A novel rigid anion receptor 1 containing thiosemicarbazone groups were synthesized. Receptor 1 displayed competitive turn-off fluorescence and colorimetric response for hydrogen pyrophosphate. This recognition process was confirmed by UV–vis, fluorescence titrations. A detailed analysis of the TD-density functional theory calculations was consistent with the observed colorimetric experiments. These experiments revealed that the colorimetric and fluorescent response is triggered by thiourea/ HP2O7 3− hydrogen bonding.

AB - A novel rigid anion receptor 1 containing thiosemicarbazone groups were synthesized. Receptor 1 displayed competitive turn-off fluorescence and colorimetric response for hydrogen pyrophosphate. This recognition process was confirmed by UV–vis, fluorescence titrations. A detailed analysis of the TD-density functional theory calculations was consistent with the observed colorimetric experiments. These experiments revealed that the colorimetric and fluorescent response is triggered by thiourea/ HP2O7 3− hydrogen bonding.

KW - Anion receptor

KW - Hydrogen bonding

KW - Hydrogen pyrophosphate

KW - Thiourea

UR - http://www.scopus.com/inward/record.url?scp=85037616027&partnerID=8YFLogxK

U2 - 10.1002/bkcs.11320

DO - 10.1002/bkcs.11320

M3 - Article

AN - SCOPUS:85037616027

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VL - 38

SP - 1435

EP - 1442

JO - Bulletin of the Korean Chemical Society

JF - Bulletin of the Korean Chemical Society

IS - 12

ER -

A Hydrogen Pyrophosphate Selective Anion Receptor Based on Thiosemicarbazone

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Keywords

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