A bromine-radical mediated three-component reaction comprising allenes, electron-deficient alkenes and allyl bromides: Facile synthesis of 2-bromo-1,7-dienes

Takashi Kippo, Ilhyong Ryu*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

9 Scopus citations

Abstract

A bromine-radical mediated three-component coupling reaction was effectively achieved by the use of allenes, electron-deficient alkenes, and allyl bromides and led to the synthesis of 2-bromo-1,7-dienes in good to high yields. This protocol was extended to the three-component process using alkylidenecyclopropane, which gave 2-bromo-1,8-diene along with alkylidenecyclopentane.

Original languageEnglish
Pages (from-to)5993-5996
Number of pages4
JournalChemical Communications
Volume50
Issue number45
DOIs
StatePublished - 7 Jun 2014

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